Citation: PENG Xiong-Xin, WANG Wen-Min, ZHONG Yu-Fei, XIAO Wei, BAO Guang-Ming, YUAN Hou-Qun. Synthesis, Crystal Structures of Two Lanthanides Complexes with 2, 6-Difluorobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 921-926. doi: 10.11862/CJIC.2020.097 shu

Synthesis, Crystal Structures of Two Lanthanides Complexes with 2, 6-Difluorobenzoic Acid

1.
School of Science, Jiangxi Agricultural University, Nanchang 330045, China
2.
Assets and Laboratory management, Jiangxi Agricultural University, Nanchang 330045, China
3.
School of Animal Science and Technology, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: YUAN Hou-Qun, hqyuan2014@126.com
Received Date: 24 October 2019
Revised Date: 26 December 2019

Figures(3)

Two complexes[Tm(dfba)₂(phen)(μ₂-dfba)]₂ (1) and[Yb(dfba)₂(phen)(μ₂-dfba)]₂ (2) (dfba^-=2, 6-difluoro-benzoate and phen=1, 10-phenanthroline) were synthesized by the reaction of 2, 6-difluorobenzote and phenan-throline with Tm³⁺ and Yb³⁺ ions, respectively. The complexes 1 and 2 were characterized by elemental analysis, FT-IR spectra, thermal gravimetric analysis (TGA) and their crystal structures were determined by single X-ray diffraction. The crystal structures analysis indicated that the complexes 1 and 2 are isostructural. Each Ln³⁺ is coordinated with two dfba^- ligands and one phen molecule to form a[Ln(dfba)₂(phen)]⁺ unit, and the neighboring two[Ln(dfba)₂(phen)]⁺ units are bridged by two different dfba^- ligands to form a binuclear molecule, [Ln(dfba)₂(phen)(μ₂-dfba)]₂ (Ln=Tm, Yb).
- 2, 6-difluorobenzoicacid,
- 1, 10-phenanthroline,
- Tm³⁺,
- Yb³⁺,
- crystal structure
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