Citation: WU Chen-Liang, LI Xiao-Qing, ZHANG He-Feng, YAN Xin-Huan. Transesterification Performance of Amorphous Iron-Based Solid Base Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 737-746. doi: 10.11862/CJIC.2020.078 shu

Transesterification Performance of Amorphous Iron-Based Solid Base Catalyst

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: YAN Xin-Huan, xhyan@zjut.edu.cn
Received Date: 23 July 2019
Revised Date: 26 December 2019

Figures(11)

Both amorphous and crystalline FeCeO_x/SiO₂ solid base catalysts were prepared by chemical reduction and co-precipitation methods, respectively. The activity of amorphous FeCeO_x/SiO₂ for the transesterification of prenyl acetate with methanol was remarkably enhanced compared with crystalline FeCeO_x/SiO₂. The catalysts were characterized by inductively coupled plasma mass spectrometry(ICP-MS), N₂ adsorption-desorption, transmission electron microscopy (TEM) in combination with selected area electron diffraction (SAED), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and temperature programmed desorption (CO₂-TPD and NH₃-TPD). As a result, the activity of the catalysts is found to be closely related to its basicity, and the amorphous FeCeO_x/SiO₂ shows higher basicity. Prenyl acetate conversion of 95% and prenyl alcohol selectivity of 96% were obtained using amorphous FeCeO_x/SiO₂ catalyst in transesterification reaction at 130℃ for 10 h. The catalyst maintained a high level of activity after 10 cycles of testing. X-ray diffraction analyses of fresh and used FeCeO_x/SiO₂ catalyst demonstrated that this catalyst is exceptionally stable, which could be of value in industrial application related to heterogeneous catalytic transesterification.
- FeCeO_x/SiO₂,
- solid base,
- amorphous,
- transesterification
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