Citation: LI Xiu-Mei, Yang Jia-Qi, PAN Ya-Ru, LIU Bo, ZHOU Shi. Syntheses, Crystal Structures and Photoluminescent Properties of Two Co(Ⅱ)/Cu(Ⅰ) Coordination Polymers Based on Bis(imidazol) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 730-736. doi: 10.11862/CJIC.2020.076 shu

Syntheses, Crystal Structures and Photoluminescent Properties of Two Co(Ⅱ)/Cu(Ⅰ) Coordination Polymers Based on Bis(imidazol) Ligands

LI Xiu-Mei ^1,, ,
Yang Jia-Qi ² ,
PAN Ya-Ru ¹ ,
LIU Bo ^2,, ,
ZHOU Shi ²

1.
Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China
2.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China

Corresponding author: LI Xiu-Mei, lixm20032006@163.com LIU Bo, 112363305@qq.com
Received Date: 30 August 2019
Revised Date: 19 December 2019

Figures(8)

Two coordination polymers, {[Co(bib)₃](ClO₄)₂}_n (1) and {[Cu₃(bix)_4.5](ClO₄)₃}_n (2), (bib=1, 4-bis(imidazol-1-yl)-butane, bix=1, 4-bis(imidazol-1-ylmethyl)benzene) have been hydrothermally synthesized by using Co(ClO₄)₂·6H₂O/Cu(ClO₄)·6H₂O, 1, 4-bis(imidazolyl-1-yl)butane/1, 4-bis(imidazolyl-1-yl) benzene and 4, 4'-(1, 3-phenylenebis(methyleneoxy))dibenzoic acid (H₂pmda) as raw materials and structurally characterized by elemental analysis, IR spectrum, fluorescence spectrum, single-crystal and powder X-ray diffraction. Complex 1 crystallizes in trigonal system, space group R\begin{document}$\bar 3$\end{document} with a=b=1.393 37(5) nm, c=1.740 54(13) nm, V=2.926 5(3) nm³, M_r=828.59, D_c=1.410 g·cm^-3, F(000)=1 293, μ=0.639 mm^-1 and Z=3. The final R₁=0.061 1 and wR₂=0.193 7 for 1 274 observed reflections with I>2σ(I). Complex 2 belongs to trigonal system too, space group P\begin{document}$\bar 3$\end{document} with a=b=2.334 41(15) nm, c=0.715 11(9) nm, V=3.374 9(5) nm³, M_r=1 561.28, D_c=1.536 g·cm^-3, F(000)=1 602, μ=1.131 mm^-1 and Z=2. The final R₁=0.043 9 and wR₂=0.109 0 for 3 167 observed reflections with I>2σ(I). Structural analyses reveal that complex 1 shows 2D network structure with 36-membered ring and complex 2 possesses 2D network structure with 84-membered ring. The intermolecular hydrogen bonding or π-π stacking interactions extend the complexes 1 and 2 into supramolecular architectures. Furthermore, we also studied the fluorescence properties of the complexes. CCDC: 1950200, 1; 1950184, 2.
- hydrothermal synthesis,
- crystal structure,
- Co(Ⅱ) complex,
- Cu(Ⅰ) complex,
- luminescence
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1.
沈阳化工大学材料科学与工程学院沈阳 110142