Citation: LIN Xing-Ye, YANG Ming-Xing, CHEN Li-Juan, XIAO Zhi-Xin, LIN Shen. Syntheses, Crystal Structures and Fluorescence Properties of Two Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 643-650. doi: 10.11862/CJIC.2020.072 shu

Syntheses, Crystal Structures and Fluorescence Properties of Two Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers

College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LIN Shen, shenlin@fjnu.edu.cn
Received Date: 1 August 2019
Revised Date: 9 January 2020

Figures(13)

Two new metal complexes, [Mn₃(Hidc)₃(DMI)₂]_n (1) (H₃idc=4, 5-imidazoledicarboxylic acid, DMI=1, 3-dimethyl-2-imidazolidinone) and[Co(tbip)(DMPU)]_n (2) (H₂tbip=5-tert-butylisophthalic acid, DMPU=N, N-dime-thylpropyleneurea), have been synthesized by urothermal method. The single crystal X-ray diffraction analysis shows that complex 1 exhibits a three-dimensional structure with square-shaped pores constructed by H₃idc and Mn(Ⅱ), and DMI molecules are filled in the pores. Complex 2 is a two-dimensional network structure constructed by H₂tbip and Co(Ⅱ) using DMPU as a template, and DMPU molecules are filled in the grids of network by coordinating with Co(Ⅱ). Solid fluorescence measurement reveals that complex 1 possesses blue fluorescence property with a strong emission at 462 nm.
- manganese(Ⅱ) complex,
- cobalt(Ⅱ) complex,
- urothermal syntheses,
- coordination polymer,
- fluorescence properties
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