Citation: HU Ming-Hua, TIAN Hua, HE Jun-Hui. Sulfur-Infused Modification and Highly Selective Enrichment of Hg²⁺ from Aqueous Solutions of CuS Hollow Nanospheres[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 695-702. doi: 10.11862/CJIC.2020.068 shu

Sulfur-Infused Modification and Highly Selective Enrichment of Hg²⁺ from Aqueous Solutions of CuS Hollow Nanospheres

HU Ming-Hua ^1,2 ,
TIAN Hua ¹ ,
HE Jun-Hui ^1,,

1.
Functional Nanomaterials Laboratory, Center for Micro/Nanomaterials and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: HE Jun-Hui, jhhe@mail.ipc.ac.cn
Received Date: 25 October 2019
Revised Date: 8 January 2020

Figures(9)

Sulfur-infused CuS hollow nanospheres (denoted as CuS@S HSs) were synthesized through a facile sublimation method. Compared to pure CuS hollow nanospheres, the sulfur-infused CuS nanospheres exhibited better enrichment performance toward Hg²⁺, one of the most toxic heavy metal pollutants in the aquatic environment. Under an optimal sulfur mass loading of w_S/w_CuS=30%, CuS@S HSs exhibited a super mercury adsorption capacity of 1 207 mg·g^-1, 229% higher than that without sulfur-infusion. Additionally, CuS@S HSs demonstrated highly rapid removal of Hg²⁺, over 99% of Hg²⁺ could be captured just within 3 min. Besides, CuS@S HSs captured Hg²⁺ selectively among other toxic heavy metal ions such as Pb²⁺, Ni²⁺, Cd²⁺, and Cr³⁺.
- mercury ion,
- copper sulfide,
- sulfur,
- adsorption,
- enrichment
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Sulfur-Infused Modification and Highly Selective Enrichment of Hg2+ from Aqueous Solutions of CuS Hollow Nanospheres

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通讯作者: 陈斌, bchen63@163.com

Sulfur-Infused Modification and Highly Selective Enrichment of Hg²⁺ from Aqueous Solutions of CuS Hollow Nanospheres