Citation: PAN Pei-Feng, CHEN Ping, FANG Ya-Nan, SHAN Qi, CHEN Ning-Na, FENG Xiao-Miao, LIU Rui-Qing, LI Pan, MA Yan-Wen. V₂O₅ Hollow Spheres as High Efficient Sulfur Host for Li-S Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(3): 575-583. doi: 10.11862/CJIC.2020.051 shu

V₂O₅ Hollow Spheres as High Efficient Sulfur Host for Li-S Batteries

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Synergistic Innovation Center forOrganic Electronics and Information Displays, Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: FENG Xiao-Miao, iamxmfeng@njupt.edu.cn MA Yan-Wen, iamywma@njupt.edu.cn
Received Date: 12 November 2019
Revised Date: 25 December 2019

Figures(6)

The V₂O₅ hollow spheres were used as a high efficient sulfur host for Li-S batteries, which was used for the storage of sulfur and restricting the shuttle effect of polysulfides. The hollow spheres had an average diameter around 500 nm, providing more space for storing sulfur, accommodating volumetric change of sulfur electrode. At the same time, V₂O₅ has a strong chemical adsorption of polysulfides, which can effectively limit the shuttle effect of polysulfides. The high capacity and excellent stability of Li-S batteries have been realized simultaneously due to the increasing of the storage of sulfur by the hollow structure and strong chemical adsorption for polysulfides by chemical bonding. The Li-S batteries with as-prepared V₂O₅/S cathode showed a high reversible capacity of 1 439 mAh·g^-1 at 0.1C and stable cycling performance with a capacity of~600 mAh·g^-1 after 300 cycles at 1C.
- lithium-sulfur batteries,
- V₂O₅ hollow spheres,
- cathode,
- shuttle effect,
- chemical adsorption
1. [1]
  Goubard-Bretesché N, Kemnitz E, Pinna N. Mater. Chem. Front., 2019, 3:2164-2184 doi: 10.1039/C9QM00325H
2. [2]
  Sun Z H, Zhang J Q, Yin L C, et al. Nat. Comm., 2017, 8:14627-14635 doi: 10.1038/ncomms14627
3. [3]
  Zhang S T, Zheng M B, Lin Z X, et al. J. Mater. Chem. A, 2014, 2:15889-15896 doi: 10.1039/C4TA03503H
4. [4]
  Ma L B, Zhang W J, Wang L, et al. ACS Nano, 2018, 12:4868-4876 doi: 10.1021/acsnano.8b01763
5. [5]
  Manthiram A, Fu Y, Chung S H, et al. Chem. Rev., 2014, 114:11751-11787 doi: 10.1021/cr500062v
6. [6]
  Zhang R, Cheng X B, Zhao C Z, et al. Adv. Mater., 2016, 28:2155-2162 doi: 10.1002/adma.201504117
7. [7]
  Xu G, Yan Q B, Kushima A, et al. Nano Energy, 2017, 31:568-574 doi: 10.1016/j.nanoen.2016.12.002
8. [8]
  Zhang J T, Hu H, Li Z, et al. Angew. Chem. Int. Ed., 2016, 55:3982-3986 doi: 10.1002/anie.201511632
9. [9]
  Shang C Q, Wei B B, Zhang X Z, et al. Mater. Lett., 2019, 236:240-243 doi: 10.1016/j.matlet.2018.10.106
10. [10]
  Liu X, Huang J Q, Zhang Q, et al. Adv. Mater., 2017, 29:1601759-1601784 doi: 10.1002/adma.201601759
11. [11]
  Zhang J, Yang C P, Yin Y X, et al. Adv. Mater., 2016, 28:9539-9544 doi: 10.1002/adma.201602913
12. [12]
  Liang X, Kwok C Y, Lodi-Marzano F, et al. Adv. Energy Mater., 2016, 6:1501636-1501645 doi: 10.1002/aenm.201501636
13. [13]
  Yue Y, Liang H. Adv. Energy Mater., 2017, 7:1602545-1602577 doi: 10.1002/aenm.201602545
14. [14]
  Wang N N, Zhang Y F, Hu T, et al. Curr. Appl. Phys., 2015, 15:493-498 doi: 10.1016/j.cap.2015.01.026
15. [15]
  Wang Y P, Nie Z W, Pan A Q, et al. J. Mater. Chem. A, 2018, 6:6792-6799 doi: 10.1039/C8TA01390J
16. [16]
  Ndiaye N M, Ngom B D, Sylla N F, et al. J. Colloid Interface Sci., 2018, 532:395-406 doi: 10.1016/j.jcis.2018.08.010
17. [17]
  Wee G, Soh H Z, Cheah Y L, et al. J. Mater. Chem., 2010, 20:6720-6725 doi: 10.1039/c0jm00059k
18. [18]
  Zhang Y F, Zheng J Q, Wang Q S, et al. RSC Adv., 2016, 6:93741-93752 doi: 10.1039/C6RA16262B
19. [19]
  Cao A M, Hu J S, Liang H P, et al. Angew. Chem. Int. Ed., 2005, 117:4465-4469 doi: 10.1002/ange.200500946
20. [20]
  Wang J Y, Tang H J, Zhang L J, et al. Nat. Energy, 2016, 1:1-9 doi: 10.1038/nenergy.2016.50
21. [21]
  Enjalbert R, Galy J. Acta Crystallogr. Sect. C, 1986, 42:1467-1469 doi: 10.1107/S0108270186091825
22. [22]
  Zhou B, He D Y. J. Raman Spectrosc., 2008, 39:1475-1481 doi: 10.1002/jrs.2025
23. [23]
  Baddour-Hadjean R, Smirnov M B, Smirnov K S, et al. Inorg. Chem., 2012, 51:3194-3201 doi: 10.1021/ic202651b
24. [24]
  Chan C K, Peng H, Twesten R D, et al. Nano Lett., 2007, 7:490-495 doi: 10.1021/nl062883j
25. [25]
  Baddour-Hadjean R, Pereira-Ramos J P. Chem. Rev., 2010, 110:1278-1319 doi: 10.1021/cr800344k
26. [26]
  Horrocks G A, Likely M F, Velazquez J M, et al. J. Mater. Chem. A, 2013, 1:15265-15277 doi: 10.1039/c3ta13690f
27. [27]
  Swiatowska-Mrowiecka J, Maurice V, Zanna S, et al. Electrochim. Acta, 2007, 52:5644-5653 doi: 10.1016/j.electacta.2006.12.050
28. [28]
  Benayad A, Martinez H, Gies A, et al. J. Electron. Spectrosc., 2006, 150:1-10 doi: 10.1016/j.elspec.2005.09.001
29. [29]
  Rao Y, Zhang L M, Shang X, et al. Appl. Surf. Sci., 2017, 423:1090-1096 doi: 10.1016/j.apsusc.2017.06.218
30. [30]
  Rout C S, Kim B H, Xu X, et al. J. Am. Chem. Soc., 2013, 135:8720-8725 doi: 10.1021/ja403232d
31. [31]
  Wang Y K, Zhang R F, Chen J, et al. Adv. Energy. Mater., 2019, 9:1900953-1900964 doi: 10.1002/aenm.201900953
32. [32]
  Zhu L, Li C C, Ren W J, et al. New J. Chem., 2018, 42:5109-5116 doi: 10.1039/C8NJ00125A
33. [33]
  Kotsis K, Staemmler V. Phys. Chem. Chem. Phys., 2006, 8:1490-1498 doi: 10.1039/b515699h
34. [34]
  Xue W, Yan Q B, Xu G, et al. Nano Energy, 2017, 38:12-18 doi: 10.1016/j.nanoen.2017.05.041
35. [35]
  Liu F, Chen Z X, Fang G Z, et al. Nano-Micro Lett., 2019, 11:25-36 doi: 10.1007/s40820-019-0256-2
36. [36]
  Wang Z Y, Wang L, Liu S, et al. Adv. Funct. Mater., 2019, 29:1901051-1901061 doi: 10.1002/adfm.201901051
37. [37]
  Chen K, Cao J, Lu Q Q, et al. Nano Res., 2017, 11:1345-1357 doi: 10.1007/s12274-017-1749-2
38. [38]
  Cao Z X, Jia J Y, Chen S N, et al. ACS Appl. Mater. Interfaces, 2019, 11:39772-39781 doi: 10.1021/acsami.9b11419
39. [39]
  Kim K, Kim P J, Youngblood J P, et al. Chem. Sus. Chem., 2018, 11:2375-2381 doi: 10.1002/cssc.201800894
40. [40]
  Tang W, Liu L L, Tian S, et al. Electrochem. Commun., 2010, 12:1524-1526 doi: 10.1016/j.elecom.2010.08.024
41. [41]
  Zhou G M, Tian H Z, Jin Y, et al. Proc. Natl. Acad. Sci. USA, 2017, 114:840-845 doi: 10.1073/pnas.1615837114
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5. [5]
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7. [7]
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V2O5 Hollow Spheres as High Efficient Sulfur Host for Li-S Batteries

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V₂O₅ Hollow Spheres as High Efficient Sulfur Host for Li-S Batteries