Citation: LIU Shun-Qiang, XIE Ming-Jiang, GUO Xue-Feng, JI Wei-Jie. Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 317-323. doi: 10.11862/CJIC.2020.037 shu

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres

1.
Department of Medicine and Chemical Engineering, Lianyungang Technical College, Lianyungang, Jiangsu 222006, China
2.
Key Laboratory of Mesoscopic Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: JI Wei-Jie, jiwj@nju.edu.cn
Received Date: 9 September 2019
Revised Date: 14 December 2019

Figures(10)

Hierarchical urchin-like TiO₂ hollow spheres comprising rutile phase of thorn and anatase phase of hollow shell was synthesized via a simple H₂O₂ assisted hydrothermal method. The effects of the pH value of preparation medium and the hydrothermal treatment time on the resulting TiO₂ morphology and structure were systematically investigated. The density of the thorns on the surface of hollow spheres can be effectively modified by tuning the pH value of preparation medium. A possible growth mechanism of the hierarchical structure was proposed. Photocatalytic degradation of methylene blue over the obtained TiO₂ hollow spheres with different density of rutile thorn was explored. It was revealed that the TiO₂ hollow spheres with less thorns outperformed the well-known photocatalyst P25-TiO₂, and were much better than the TiO₂ hollow spheres with more thorns and the smooth TiO₂ hollow spheres.
- inorganic nonmetallic materials,
- hydrothermal method,
- photocatalysis,
- titanium dioxide,
- methylene blue,
- mixed-phase,
- hollow sphere
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO2 Hollow Spheres

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Degradation of Methylene Blue of Hierarchical Mixed-Phase Urchin-like TiO₂ Hollow Spheres