Citation: WU Guo-Zhi, WANG Peng-Fei, LI Shan-Qing, FANG Xiao-Long. Metal Complexes Based on 3-Nitrophthalic Acid Involving in Situ Decarboxylaton: Syntheses, Crystal Structures and Physical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 226-232. doi: 10.11862/CJIC.2020.035 shu

Metal Complexes Based on 3-Nitrophthalic Acid Involving in Situ Decarboxylaton: Syntheses, Crystal Structures and Physical Properties

1.
Key Laboratory of Micro-Nano Powder and Advanced Energy Materials of Anhui Higher Education Institute, School of Materials and Environmental Engineering, Chizhou University, Chizhou, Anhui 247000, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com LI Shan-Qing, 103247284@qq.com
Received Date: 30 May 2019
Revised Date: 27 October 2019

Figures(8)

Two metal complexes, [Zn(3-NBA)(trz)]_n (1) and[Pb(3-NBA)(phen)₂]NO₃ (2), have been constructed through hydrothermal reaction using 3-nitrophthalic acid (3-NPAH₂), phen (1, 10-phenanthroline) or 1, 2, 4-triazole (Htrz), and ZnSO₄·7H₂O or Pb(NO₃)₂. During the reaction, the 3-HNBA resulted from the in situ decarboxylation of 3-nitrophthalic acid, and the experimental results have been confirmed by the theoretical calculation. Complexes 1~2 have been characterized by IR spectra, PXRD, elemental analyses and thermogravimetric analyses. Single-crystal X-ray diffraction analyses reveal that complex 1 exhibits a two-dimensional (2D) layered structure, which packs through weak N-O…π interactions. Complex 2 has a monomeric structure, which is assembled to a three-dimensional (3D) supramolecular structure through weak π…π interactions. Furthermore, the solid-state fluorescence of complexes 1~2 was recorded at room temperature.
- metal complex,
- crystal structure,
- fluorescent property,
- in situ reaction
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沈阳化工大学材料科学与工程学院沈阳 110142