Citation: WANG Jing-Jing, ZAHNG Jiang, WANG Jin-Yue, WANG Lu, LI Xuan-Ke. Effect of Heat Treatment on Structure and Lithium Ion Storage Properties of N-Rich Carbon Nanofibers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 31-39. doi: 10.11862/CJIC.2020.026 shu

Effect of Heat Treatment on Structure and Lithium Ion Storage Properties of N-Rich Carbon Nanofibers

WANG Jing-Jing ^1,2 ,
ZAHNG Jiang ^1,2,, ,
WANG Jin-Yue ^1,2 ,
WANG Lu ² ,
LI Xuan-Ke ^1,2

1.
The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
2.
Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan University of Science and Technology, Wuhan 430081, China

Corresponding author: ZAHNG Jiang, zhangjiang@wust.edu.cn
Received Date: 29 July 2019
Revised Date: 13 November 2019

Figures(11)

Carbon nanofibers (CNFs) were prepared from polyacrylonitrile (PAN) via electrospinning followed by stabilization and carbonization. The morphology and structure of the carbon nanofibers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray photo-electron spectroscopy (XPS). The electrochemical properties were investigated as anode material in lithium ion batteries (LIBs). A systematic study was made to confirm the effect of the nitrogen species on the performance of lithium ion storage and the capacities of anodes in LIBs. It is noticed that the structure change has a great influence on the storage position of lithium ion in CNFs electrode. The results showed that lithium ions can be stored not only between the graphitized carbon layers, but also in the defects caused by the functionalization of nitrogen, the latter was mainly because the improvement of the electrochemical performance of LIBs due to the N-doping of carbon materials. There is a strong correlation between the atomic structure, with lithium ion storage behavior and electrochemical properties of anode materials. It is revealed that thermal annealing had an important effect on the atomic structure and morphology of CNFs. A high temperature treatment promoted graphitization and improved electrical conductivity through the growth of aromatic groups. During the transition from amorphous carbon to graphite structure at high temperature, defects and heteroatoms were removed with the decrease of nitrogen contents. Therefore, CNFs obtained at high carbonization temperature may have high lithium ion storage capacity between graphene layers, but it failed to provide attractive capacity due to low nitrogen content. An optimized carbonization temperature of 600℃ was identified, the electrode gave rise to a sufficiently high nitrogen content and thus a high capacity about 560 mAh·g^-1 after 200 cycles at the current density of 0.1 A·g^-1, the specific capacity at the high current density of 1 A·g^-1 even still remained 200 mAh·g^-1 after 1 000 cycles.
- anode materials,
- carbon nanofiber,
- electrospinning,
- PAN,
- N-doping
1. [1]
  Zhang B, Kang F Y, Tarascon J M, et al. Prog. Mater Sci., 2016, 76:319-380 doi: 10.1016/j.pmatsci.2015.08.002
2. [2]
  Liu Q, Zhu J H, Zhang L W, et al. Renewable Sustainable Energy Rev., 2018, 81:1825-1858 doi: 10.1016/j.rser.2017.05.281
3. [3]
  Goodenough J B. Energy Environ. Sci., 2014, 7(1):14-18
4. [4]
  Frackowiak E, Béguin F. Carbon, 2001, 39(6):937-950 doi: 10.1016/S0008-6223(00)00183-4
5. [5]
  Yoo E, Kim J, Hosono E, et al. Nano Lett., 2008, 8(8):2277-2282 doi: 10.1021/nl800957b
6. [6]
  Mitchell R R, Gallant B M, Thompson C V, et al. Energy Environ. Sci., 2011, 4(8):2952-2958 doi: 10.1039/c1ee01496j
7. [7]
  Wen Z H, Wang Q, Zhang Q, et al. Adv. Funct. Mater., 2007, 17(15):2772-2778 doi: 10.1002/adfm.200600739
8. [8]
  Zheng G Y, Yang Y, Cha J J, et al. Nano Lett., 2011, 11(10):4462-4467 doi: 10.1021/nl2027684
9. [9]
  Wu L, Lu H Y, Xiao L F, et al. J. Mater. Chem. A, 2014, 2(39):16424-16428 doi: 10.1039/C4TA03365E
10. [10]
  Han Y, Zou J, Li Z, et al. ACS Nano, 2018, 12(5):4835-4843 doi: 10.1021/acsnano.8b01558
11. [11]
  Guo J, Liu J, Dai H, et al. J. Colloid Interface Sci., 2017, 507:154-161 doi: 10.1016/j.jcis.2017.07.117
12. [12]
  Paek S M, Yoo E, Honma I. Nano Lett., 2009, 9(1):72-75 doi: 10.1021/nl802484w
13. [13]
  Yu C J, Masarapu C, Rong J P, et al. Adv. Mater., 2009, 21(47):4793-4797 doi: 10.1002/adma.200901775
14. [14]
  Hu L B, Wu H, La Mantia F, et al. ACS Nano, 2010, 4(10):5843-5848 doi: 10.1021/nn1018158
15. [15]
  Zhang B, Zheng Q B, Huang Z D, et al. Carbon, 2011, 49(13):4524-4534 doi: 10.1016/j.carbon.2011.06.059
16. [16]
  Qie L, Chen W M, Wang Z H, et al. Adv. Mater., 2012, 24(15):2047-2050 doi: 10.1002/adma.201104634
17. [17]
  Su D S, Schlgl R. ChemSusChem, 2010, 3(2):136-168 doi: 10.1002/cssc.200900182
18. [18]
  Mao X W, Hatton T A, Rutledge G C. Curr. Org. Chem., 2013, 17(13):1390-1401 doi: 10.2174/1385272811317130006
19. [19]
  Jiang S H, Chen Y M, Duan G G, et al. Polym. Chem., 2018, 9(20):2685-2720 doi: 10.1039/C8PY00378E
20. [20]
  Wang C H, Kaneti Y V, Bando Y, et al. Mater. Horiz., 2018, 5(3):394-407 doi: 10.1039/C8MH00133B
21. [21]
  Yuan C P, Wu Q, Shao Q, et al. J. Colloid Interface Sci., 2018, 517:72-79 doi: 10.1016/j.jcis.2018.01.095
22. [22]
  Kim C, Yang K S, Kojima M, et al. Adv. Funct. Mater., 2006, 16(18):2393-2397 doi: 10.1002/adfm.200500911
23. [23]
  ZHANG Ye-Qiong, CONG Ye, ZHANG Jing, et al. Chinese J. Inorg. Chem., 2018, 34(8):41-47
24. [24]
  Li P, Hwang J Y, Sun Y K, et al. ACS Nano, 2019, 13(2):2624-2633
25. [25]
  Sun F G, Wang J T, Chen H C, et al. ACS Appl. Mater. Interfaces, 2013, 5(12):5630-5638 doi: 10.1021/am400958x
26. [26]
  Oh J, Lee J, Jeon Y, et al. ACS Sustainable Chem. Eng., 2019, 7(1):306-314 doi: 10.1021/acssuschemeng.8b03390
27. [27]
  Wang S X, Yang L P, Stubbs L P, et al. ACS Appl. Mater. Interfaces, 2013, 5(23):12275-12282 doi: 10.1021/am4043867
28. [28]
  Xia J, Jiang K Z, Xie J J, et al. Chem. Eng. J., 2019, 359:1244-1251 doi: 10.1016/j.cej.2018.11.053
29. [29]
  Wang Y, Santiago-Avilés J J, et al. IEEE Trans. Nanotechnol., 2003, 2(1):39-43 doi: 10.1109/TNANO.2003.808510
30. [30]
  Wang Y, Serrano S, Santiago-Avilés J J, Furlan R, et al. Synth. Met., 2003, 138(3):423-427 doi: 10.1016/S0379-6779(02)00472-1
31. [31]
  Wei D C, Liu Y Q, Wang Y, et al. Nano Lett., 2009, 9(5):1752-1758 doi: 10.1021/nl803279t
32. [32]
  Laffont L, Monthioux M, Serin V, et al. Carbon, 2004, 42(12):2485-2494
33. [33]
  Plomp A J, Su D S, De Jong K P, et al. J. Phys. Chem. C, 2009, 113(22):9865-9869 doi: 10.1021/jp900637q
34. [34]
  Liu Y C, Zhang N, Liu X B, et al. Energy Storage Mater., 2017, 9:170-178 doi: 10.1016/j.ensm.2017.07.012
35. [35]
  Su F B, Poh C K, Chen J S, et al. Energy Environ. Sci., 2011, 4(3):717-724 doi: 10.1039/C0EE00277A
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
7. [7]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
8. [8]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
9. [9]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
11. [11]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
12. [12]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
13. [13]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
14. [14]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
15. [15]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
16. [16]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
17. [17]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
18. [18]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
19. [19]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
20. [20]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(646)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142