Citation: ZHU Ning, PAN Xun, LIN Sen, YANG Yu-Ping, XIN Xiu-Lan, LI Zhong-Feng, ZHANG Fan, JIN Qiong-Hua. Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 183-191. doi: 10.11862/CJIC.2020.015 shu

Syntheses, Structures and Terahertz Time-Domain Spectroscopy of Two Diimine-Copper(Ⅰ)-Phosphine Complexes

ZHU Ning ^1,2 ,
PAN Xun ¹ ,
LIN Sen ¹ ,
YANG Yu-Ping ³ ,
XIN Xiu-Lan ⁴ ,
LI Zhong-Feng ¹ ,
ZHANG Fan ^1,, ,
JIN Qiong-Hua ^1,2,,

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: ZHANG Fan, 3938@cnu.edu.cn JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 28 May 2019
Revised Date: 11 October 2019

Figures(11)

Herein, two novel copper(Ⅰ) complexes, [Cu(PPh₃)₂(dppz)]Ⅰ (1) and[Cu₂(dppm)₂(dppz)₂]Cl₂ (2) (PPh₃=triphenylphosphine, dppz=dipyrido[3, 2-a:2', 3'-c]phenazine, dppm=bis(diphenylphosphino) methane) have been synthesized, and the characterization of the complexes was carried out through single-crystal X-ray diffraction, elemental analysis, IR, ¹H/³¹P NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). The results show that 1 is a mononuclear complex. The central Cu(Ⅰ) builds a distorted tetrahedral geometry by coordinating with two phosphine ligands (PPh₃) and one chelating N-donor ligand (dppz). Different from 1, 2 exhibits a dinuclear structure which was obtained by the reaction of CuCl and dppm with dppz in 1:1:1 molar ratio, where the diphosphine ligand (dppm) was utilized as a bridging ligand coordinating to two copper(Ⅰ) atoms. The luminescent spectra show that the emission mechanism belongs to metal-to-ligand charge transfer (MLCT). At the same time, the terahertz (THz) time-domain spectroscopy was used to represent these two complexes as well as the corresponding ligands.
- copper(Ⅰ) complex,
- structures,
- fluorescence,
- terahertz (THz) time-domain spectroscopy,
- dipyrido[3, 2-a:2', 3'-c]phenazine
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