Citation: SUN Yun-Po, XIE Jian, ZHAO Xin-Bing, ZHUANG Da-Gao, ZHANG Gen-Lin. Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 106-112. doi: 10.11862/CJIC.2020.008 shu

Prussian Blue Cathode Material: Preparation by Ion-Exchange Method and Electrochemical Potassium-Storage Performance

1.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
2.
Shanghai Han Xing Science and Technology Co., Ltd., Shanghai 201322, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 4 July 2019
Revised Date: 11 November 2019

Figures(5)

Na-doped K-based Prussian blue (NKPB) material (K_1.9Na_0.1Mn[Fe(CN)₆]·0.4H₂O) was prepared by ion-exchange method using KCl and Na-based Prussian blue (NPB) material(Na_2-xMn[Fe(CN)₆]_z·yH₂O) as the precursors. The electrochemical tests reveal that compared with the K-based Prussian blue (KPB) material K_1.85Mn[Fe(CN)₆]_0.98□_0.02·0.7H₂O (□ is the[Fe(CN)₆] vacancy) prepared by a conversional coprecipitation route, the NKPB prepared by ion-exchange method shows higher capacity (the initial discharge capacity at 0.1C reached 136.3 mAh·g^-1), longer cycle life (the capacity retention after 100 cycles at 0.5C was 96.1%), and better rate capability (the capacities at 5C and 10C were 87.6 and 68.4 mAh·g^-1, respectively). The outstanding electrochemical performance of the NKPB material is ascribed to its high K content, good crystal integrity, Na-ion doping, nanosized particles and the unique open framework structure.
- potassium-ion battery,
- cathode material,
- Prussian blue material,
- ion-exchange method,
- electrochemical performance
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