Citation: LI Ling-Yan, LI Man, LI Lei, YU Yun-Yao, PAN Shang-Ke, PAN Jian-Guo. Synthesis, Crystal Structures and Photophysical Properties of Manganese(Ⅱ) Complexes Based on Imidazole Ionic Liquids[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2275-2283. doi: 10.11862/CJIC.2019.264 shu

Synthesis, Crystal Structures and Photophysical Properties of Manganese(Ⅱ) Complexes Based on Imidazole Ionic Liquids

Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, School of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Corresponding author: PAN Jian-Guo, panjianguo@nbu.edu.cn
Received Date: 13 June 2019
Revised Date: 16 September 2019

Figures(7)

Two low dimensional Mn(Ⅱ) complexes, (C₄H₇N₂)[MnCl₃(H₂O)] (1) and[(C₄H₇N₂)₂] [MnBr₄] (2), with different structures and optical properties have been synthesized by changing the types of imidazole ionic liquids species at room temperature. The complexes 1 and 2 have been characterized by single-crystal X-ray diffraction, photoluminescence, X-ray excitation emission spectrum, decay curve and thermogravimetric analysis. The X-ray diffraction results show that 1 crystallizes in the monoclinic space group P2₁/n, and the central Mn(Ⅱ) has an octahedral configuration, and 2 crystallizes in the triclinic space group P1, and the central Mn(Ⅱ) has a tetrahedron configuration. Under the UV light (λ_ex=370 nm), solid complexes 1 and 2 emitted deep-red and green emission, respectively. The photoluminescence decay times were 200.11 and 37.23 μs, respectively, and their quantum yield were 23.52% and 5.54%, respectively. Moreover, under the excitation of X-ray, they showed the better X-ray fluorescence performance.
- Mn(Ⅱ) complex,
- crystal structure,
- hydrogen bond,
- photoluminescence
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