Citation: HU Su-Fang, WANG Yan, MA Jing-Hong, LI Rui-Feng. One-Step Synthesis of High-Silica ZSM-5 in the Absence of Organic Amine[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2253-2259. doi: 10.11862/CJIC.2019.263 shu

One-Step Synthesis of High-Silica ZSM-5 in the Absence of Organic Amine

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: MA Jing-Hong, majinghong@tyut.edu.cn
Received Date: 8 May 2019
Revised Date: 30 July 2019

Figures(6)

The plate-like high-silica ZSM-5 zeolite (n_SiO₂/n_Al₂O₃>90) with uniform morphology was synthesized by hydrothermal method at a lower crystallization temperature (130℃) in the absence of organic amine and seed. The effects on ratio of the amount of substance of reactants on the synthesis of high-silica ZSM-5 zeolite were systematically investigated. The synthesized high-silica ZSM-5 zeolite was characterized by XRD, FT-IR, SEM, N₂ adsorption/desorption and ²⁹Si MAS NMR techniques. Results confirmed that the synthesized ZSM-5 zeolite (n_C₂H₅OH/n_SiO₂=2.8, n_Na₂O/n_SiO₂=0.14, n_SiO₂/n_Al₂O₃=150) exhibited high crystallinity of the product. The specific surface area and micropore volume were 409 m²·g^-1 and 0.14 cm³·g^-1. ²⁹Si MAS NMR analysis showed that the n_SiO₂/n_Al₂O₃ was 96.4.
- absence of organic amine,
- ZSM-5 zeolite,
- high-silica,
- hydrothermal synthesis
1. [1]
  Richards R E, Rees L V C. Langmuir, 1987, 3(3):335-340
2. [2]
  Nguyen C M, Reyniers M F, Marin G B. J. Catal., 2015, 322:91-103 doi: 10.1016/j.jcat.2014.11.013
3. [3]
  Bjrgen M, Svelle S, Joensen F, et al. J. Catal., 2007, 249(2):195-207 doi: 10.1016/j.jcat.2007.04.006
4. [4]
  Svelle S, Joensen F, Nerlov J, et al. J. Am. Chem. Soc., 2006, 128(46):14770-14771 doi: 10.1021/ja065810a
5. [5]
  Degnan T F, Chitnis G K, Schipper P H. Microporous Mesoporous Mater., 2000, 35-6(2):245-252
6. [6]
  Bjørgen M, Joensen F, Holm M S, et al. Appl. Catal. A Gen., 2008, 345(1):43-50 doi: 10.1016/j.apcata.2008.04.020
7. [7]
  GAO He-Xin, LI Peng, DU Yan-Ze, et al. Chinese J. Inorg. Chem., 2017, 33(7):1249-1256
8. [8]
  Argauer R J, Landolt G R. US Patent, 3702886. 1972-11-14.
9. [9]
  Sang S, Chang F, Liu Z, et al. Catal. Today, 2004, 93:729-734
10. [10]
  Kirschhock C E A, Ravishankar R, Verspeurt F, et al. J. Phys. Chem. B, 1999, 103(24):4965-4971 doi: 10.1021/jp990297r
11. [11]
  Xu W, Dong J, Li J, et al. J. Chem. Soc., Chem. Commun., 1990(10):755-756 doi: 10.1039/c39900000755
12. [12]
  Boxhoorn G, Van Santen R A, Van Erp W A, et al. J. Chem. Soc., Chem. Commun., 1982(4):264-265 doi: 10.1039/c39820000264
13. [13]
  Burkett S L, Davis M E. Chem. Mater., 1995, 7(5):920-928 doi: 10.1021/cm00053a017
14. [14]
  Grose R W, Flanigen E M. US Patent, 4257885. 1981-03-24
15. [15]
  LI He-Zuan, XIANG Shou-He, WU De-Ming, et al. Chem. J. Chinese Universities, 1981, 2(4):124-126
16. [16]
  Pan H, Pan Q, Zhao Y, et al. Ind. Eng. Chem. Res., 2010, 49(16):7294-7302 doi: 10.1021/ie100191a
17. [17]
  Yu Q, Meng X, Liu J, et al. Microporous Mesoporous Mater., 2013, 181:192-200 doi: 10.1016/j.micromeso.2013.07.034
18. [18]
  Razavian M, Fatemi S, Komasi M. Mater. Res. Bull., 2015, 65:253-259 doi: 10.1016/j.materresbull.2015.01.062
19. [19]
  Kim S D, Noh S H, Park J W, et al. Microporous Mesoporous Mater., 2006, 92(1/2/3):181-188
20. [20]
  Kim S D, Noh S H, Seong K H, et al. Microporous Mesoporous Mater., 2004, 72(1/2/3):185-192
21. [21]
  Zhang D, Wang R, Yang X. Microporous Mesoporous Mater., 2009, 126(1/2):8-13
22. [22]
  Kalipcilar H, Culfaz A. Cryst. Res. Technol., 2001, 36(11):1197-1207 doi: 10.1002/1521-4079(200111)36:11<1197::AID-CRAT1197>3.0.CO;2-D
23. [23]
  Yin Z, Chen Y, Wang Z, et al. Adv. Mater. Res., 2015, 1096:176-180 doi: 10.4028/www.scientific.net/AMR.1096.176
24. [24]
  Hartanto D, Saputro O, Utomo W P, et al. Asian J. Chem., 2016, 28(1):211 doi: 10.14233/ajchem.2016.19348
25. [25]
  Shiralkar V P, Clearfield A. Zeolites, 1989, 9(5):363-370
26. [26]
  Uguina M A, De Lucas A, Ruiz F, et al. Ind. Eng. Chem. Res., 1995, 34(2):451-456 doi: 10.1021/ie00041a004
27. [27]
  Narayanan S, Sultana A, Le Q T, et al. Appl. Catal. A Gen., 1998, 168(2):373-384 doi: 10.1016/S0926-860X(97)00368-2
28. [28]
  WANG Dian-Zhong, SHU Xing-Tian, HE Ming-Yuan. Pet. Process. Petrochem., 2002, 33(6):16-18 doi: 10.3969/j.issn.1005-2399.2002.06.004
29. [29]
  LI Hong-Yuan, LIANG Juan, YING Mu-Liang, et al. Chin. J. Catal., 1983, 4(3):244-247
30. [30]
  Coudurier G, Naccache C, Vedrine J C. J. Chem. Soc., Chem. Commun., 1982(24):1413-1415 doi: 10.1039/c39820001413
31. [31]
  Ravishankar R, Kirschhock C, Schoeman B J, et al. J. Phys. Chem. B, 1998, 102(15):2633-2639 doi: 10.1021/jp973147u
32. [32]
  GAO Min, LIU Chun-Yan, WANG Ren, et al. Chemistry, 2009, 72(12):1097-1103
33. [33]
  Nada M H, Larsen S C. Microporous and Mesoporous Mater., 2017, 239:444-452 doi: 10.1016/j.micromeso.2016.10.040
34. [34]
  Huang X, Wang Z. Chin. J. Catal., 2011, 32(11):1702-1711
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