Synthesis and Gelation Ability of Spin-Crossover Iron(Ⅱ) Alkyl Imidazole Complexes
- Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Citation: WANG Ya-Qin, ZHANG Hai-Xia, ZHANG Shu-Heng, HE Wei, GE Fang-Yuan, CHEN Yu-Xin, GU Zhi-Guo. Synthesis and Gelation Ability of Spin-Crossover Iron(Ⅱ) Alkyl Imidazole Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(12): 2260-2268. doi: 10.11862/CJIC.2019.254
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All H atoms and BF4- anions have been removed for clarity; the grey, blue and purple ellipsoids represent C, N, and Fe, respectively; Intramolecular π-π interactions are illustrated as green dashed lines
Intramolecular C-H…π interactions between benzene ring and benzene ring are illustrated as green dashed lines; Intramolecular C-H…π interactions between imidazole ring and alkyl chain are illustrated as red dashed lines
Magnification times: (a) ×1 300; (b) ×2 000; (c) ×60 000; (d) ×90 000