Citation: ZHANG Nan, YUAN Juan, LIU Mei-Jiao, JIN Yi-Shu, KOU Hui-Zhong. Synthesis and Magnetism of Binuclear Fe(Ⅱ) Complexes Based on Bis-pyridylhydrazone Schiff Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2066-2072. doi: 10.11862/CJIC.2019.234 shu

Synthesis and Magnetism of Binuclear Fe(Ⅱ) Complexes Based on Bis-pyridylhydrazone Schiff Base Ligands

Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: KOU Hui-Zhong, kouhz@mail.tsinghua.edu.cn
Received Date: 14 August 2019
Revised Date: 27 September 2019

Figures(4)

Two binuclear Fe(Ⅱ) complexes of bis-pyridylhydrazone Schiff base ligands HL^x (x=1, 2) have been successfully synthesized and characterized by infrared spectroscopy, X-ray single crystal diffraction and magnetic susceptibility measurements. Single-crystal structural determinations reveal that the Fe(Ⅱ) ion is chelated by two pyridylhydrazone Schiff base ligands to form a FeN₄O₂ distorted octahedral structure and four free perchlorates serve as charge balancing anions. Intermolecular π…π stacking is present in the complexes, connecting adjacent[Fe₂(HL^x)₂]⁴⁺ cations to form supramolecular chains. Magnetic susceptibility measurement shows that the complexes are both in the high-spin state, meanwhile complex 2 exhibits weak intermolecular ferromagnetic coupling.
- dinuclear iron(Ⅱ) complex,
- crystal structure,
- magnetism,
- high-spin,
- hydrazine
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