Citation: LAN Hong-Hong, LI Xiao-Tong, CHU Wen-Juan, XU Chun-Ying, JI Bao-Ming. Syntheses, Crystal Structures and Luminescence Properties of Two Zn(Ⅱ) Coordination Polymers Based on Flexible Bisbenzimidazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1896-1902. doi: 10.11862/CJIC.2019.210 shu

Syntheses, Crystal Structures and Luminescence Properties of Two Zn(Ⅱ) Coordination Polymers Based on Flexible Bisbenzimidazole Ligand

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China
2.
Patent Examination Cooperation(Henan) Center of the Patent Office, CNIPA, Zhengzhou 470018, China
3.
Technology Center, China Tobacco Henan Industrial Co., Ltd., Zhengzhou 450000, China

Corresponding author: JI Bao-Ming, lyhxxjbming@126.com
Received Date: 11 June 2019
Revised Date: 12 July 2019

Figures(6)

Two new coordination polymers, {[Zn(bmb)_0.5(btec)_0.5(H₂O)]·H₂O}_n (1) and {[Zn₂(bmb)₂(dcbp)]·5H₂O}_n (2) were synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses and powder X-ray diffractions (bmb=1, 4-bis(2-methylbenzimidazol-1-ylmethyl) benzene, H₄btec=1, 2, 4, 5-benzenetetracarboxylic acid, H₄dcbp=4-(3, 4-dicarboxybenzoyl)phthalic acid). Structural analyses reveal that both polymers 1 and 2 exhibit complicated 3D frameworks in which bmb acts as linker with μ₂-η¹:η¹ coordination mode. Thermal stabilities and solid-state luminescence at room temperature of 1 and 2 also were investigated.
- coordination polymers,
- zinc,
- crystal structure,
- luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142