Citation: LI Yu, PAN Guang-Min, ZOU Xun-Zhong, FENG An-Sheng, YOU Ao, QIU Wen-Da. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1853-1860. doi: 10.11862/CJIC.2019.206 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks

LI Yu ¹ ,
PAN Guang-Min ² ,
ZOU Xun-Zhong ¹ ,
FENG An-Sheng ¹ ,
YOU Ao ^1,, ,
QIU Wen-Da ^1,,

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Techlonogy, Guangzhou 510006, China

Corresponding author: YOU Ao, youao321@163.com QIU Wen-Da, Qiuwdgq@hotmail.com
Received Date: 23 May 2019
Revised Date: 14 June 2019

Figures(9)

One 0D zinic(Ⅱ) and two 1D manganese(Ⅱ) coordination compounds, namely[Zn(H₂biim)₂(H₂O)₂] [Zn(HL)(Hbiim)(H₂O)]₂·8H₂O (1), [Mn(μ-HL)(phen)(H₂O)]_n (2) and {[Mn(μ-HL)(2, 2'-bipy)(H₂O)]·0.5(2, 2'-bipy)}_n (3) have been constructed hydrothermally using H₃L (H₃L=4-(6-carboxy-pyridin-3-yl)-isophthalic acid), H₂biim (H₂biim=2, 2'-biimidazole), phen (phen=1, 10-phenanthroline), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and zinc or manganese chlorides. Single-crystal X-ray diffraction analyses reveal that three compounds crystallize in the monoclinic system, space groups P2₁/n or P2₁/c. Compound 1 shows a 0D structure composed of three monomer Zn(Ⅱ) units, which is arranged into a 3D supramolecular framework through O-H…O/N or N-H…O hydrogen bonds. Compounds 2 and 3 feature a 1D metal-organic chain, which is assembled to a 2D supramolecular network through O-H…O hydrogen bond. The luminescent and magnetic properties for three compounds were also investigated.
- coordination polymer,
- pyridine-tricarboxylic acid,
- luminescent properties,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142