Citation: GAO Duan, CHENG Li-Hong, CHEN Bao-Jiu, LIU Sheng-Yi, LI Xiang-Ping, SUN Jia-Shi, XU Sai, ZHANG Jin-Su. Effect of Microwave-Assisted Hydrothermal Reaction Parameters on Phase, Morphology and Luminescence Properties of NaYF₄: Dy³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1623-1634. doi: 10.11862/CJIC.2019.203 shu

Effect of Microwave-Assisted Hydrothermal Reaction Parameters on Phase, Morphology and Luminescence Properties of NaYF₄: Dy³⁺ Phosphors

College of Science, Dalian Maritime University, Dalian, Liaoning 116026, China

Corresponding author: CHENG Li-Hong, cheng-lihong@126.com
Received Date: 30 April 2019
Revised Date: 8 June 2019

Figures(16)

The disadvantage of the traditional hydrothermal method was the poor repeatability. Therefore, the conclusions of the influence of various parameters on the morphology of rare earth doped NaYF₄ prepared by the traditional hydrothermal method reported by different research groups in the literature were different. In order to clarify the effects of hydrothermal parameters on the structure and morphology of rare earth doped NaYF₄, Dy³⁺ doped NaYF₄ phosphors were prepared by microwave hydrothermal method with good reproducibility and controllability. The effects of various parameters on the structure, morphology and luminescence of the products were systematically studied. The reproducible NaYF₄:Dy³⁺ samples were rapidly prepared by microwave-assisted hydrothermal method. The effects of reaction parameters on the crystal phase, morphology and luminescence properties of NaYF₄:Dy³⁺ phosphors were investigated. The results show that the microwave hydrothermal reaction time don't affect the crystal phase, morphology and spectral properties of the as-prepared phosphors. The increase of Dy³⁺ concentration do not change the crystal phase and morphology of the samples, but the luminescence intensity changes. The trends of luminescence intensity first increased and then decreased. The maximum luminescence intensity was obtained when the Dy³⁺ concentration was 1%(n/n). The electric multipole interaction index obtained according to the specific theoretical basis was 6. It is shown that the interaction between Dy³⁺ is dipole-dipole interaction. The effects of the type and amounts of surfactant on the NaYF₄:Dy³⁺ crystal phase were investigated. It was observed when Na₃Cit·2H₂O and CTAB were used as surfactants, hexagonal phase NaYF₄:Dy³⁺ phosphors were prepared. The amounts of Na₃Cit·2H₂O and CTAB were increased and the crystal phase of the sample was not changed. When EDTA-2Na was used as the surfactant, the transition from the hexagonal phase to the cubic phase crystal phase occurred as the amounts of the EDTA-2Na increased. As the amounts of surfactants continue to increase, the size of the sample decreased. Under the excitation of 350 nm, Dy³⁺ emission peaks appeared. The blue light emission peak centered at 479 nm, which corresponds to the ⁴F_9/2→⁶H_15/2 transition of Dy³⁺. The green light emission peak centered at 572 nm, which corresponds to the ⁴F_9/2→⁶H_13/2 transition of Dy³⁺.
- microwave-assisted hydrothermal method,
- reaction time,
- Dy³⁺,
- concentration,
- Na₃Cit · 2H₂O,
- CTAB,
- EDTA-2Na
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Effect of Microwave-Assisted Hydrothermal Reaction Parameters on Phase, Morphology and Luminescence Properties of NaYF4: Dy3+ Phosphors

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通讯作者: 陈斌, bchen63@163.com

Effect of Microwave-Assisted Hydrothermal Reaction Parameters on Phase, Morphology and Luminescence Properties of NaYF₄: Dy³⁺ Phosphors