Citation: YANG Hong-Li, CHEN Fang, ZHANG Dan, HE Xiong, ZHANG Xiu-Qing. Syntheses, Crystal Structures, Thermal Stabilities and Fluorescence Properties of Silver(Ⅰ) and Cadmium(Ⅱ) Complexes Based on 1, 2, 4-Benzenetricarboxylic Acid and 2, 2'-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1579-1585. doi: 10.11862/CJIC.2019.193 shu

Syntheses, Crystal Structures, Thermal Stabilities and Fluorescence Properties of Silver(Ⅰ) and Cadmium(Ⅱ) Complexes Based on 1, 2, 4-Benzenetricarboxylic Acid and 2, 2'-Bipyridine

College of Chemistry and Bioengineering, Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: ZHANG Xiu-Qing, glutchem@163.com
Received Date: 11 March 2019
Revised Date: 7 June 2019

Figures(10)

Two complexes, [Ag(H₂btc)(bpy)] (1) and[Cd(Hbtc)(bpy)(H₂O)₂]_n (2) (H₃btc=1, 2, 4-benzenetricarboxylic acid, bpy=2, 2'-bipyridine), were synthesized under pH-controlled hydrothermal conditions and characterized by X-ray single crystal diffraction, IR spectra, thermal gravimetric analysis (TGA) and fluorescence spectroscopy. The results show that complex 1 is a zero-dimensional mononuclear small molecule structure, and 2 is a one-dimensional chain structure. Fluorescence studies showed that both complexes have fluorescent properties.
- 1, 2, 4-benzenetricarboxylic acid,
- 2, 2'-bipyridine,
- crystal structures,
- fluorescence
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