Citation: ZOU Xun-Zhong, WU Jiang, GU Jin-Zhong, ZHAO Na, FENG An-Sheng, LI Yu. Syntheses of Two Nickel(Ⅱ) Coordination Compounds Based on a Rigid Linear Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1705-1711. doi: 10.11862/CJIC.2019.190 shu

Syntheses of Two Nickel(Ⅱ) Coordination Compounds Based on a Rigid Linear Tricarboxylic Acid

ZOU Xun-Zhong ¹ ,
WU Jiang ² ,
GU Jin-Zhong ^3,, ,
ZHAO Na ¹ ,
FENG An-Sheng ¹ ,
LI Yu ^1,,

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
Key Laboratory for Tibet Plateau Phytochemistry of Qinghai Province, School of Pharmacy, Qinghai University for Nationalities, Xining 810007, China
3.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GU Jin-Zhong, gujzh@lzu.edu.cn LI Yu, liyuletter@163.com
Received Date: 15 April 2019
Revised Date: 25 May 2019

Figures(7)

Zero dimensional dinuclear nickel(Ⅱ) coordination compound and 1D chain nickel(Ⅱ) coordination polymer, namely[Ni₂(μ-HL)₂(2, 2'-bipy)₂(H₂O)₄]·6H₂O (1) and {[Ni(μ-HL)(2, 2'-bipy)(H₂O)₂]·H₂O}_n (2), have been constructed hydrothermally using 2, 5-di(4-carboxylphenyl)nicotinic acid (H₃L), 2, 2'-bipyridine (2, 2'-bipy), and nickel chloride at 120 or 160℃, respectively. Single-crystal X-ray diffraction analyses revealed that both complexes crystallize in the triclinic system, space group P1. Complex 1 discloses a discrete dimer structure, which is assembled to a 3D supramolecular framework through O-H…O/N hydrogen bond. Complex 2 has a chain structure. Structural differences between compounds 1 and 2 may be attributed to the different hydrothermal reaction temperature. Magnetic studies for complex 2 demonstrate an antiferromagnetic coupling between the adjacent Ni(Ⅱ) centers.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- magnetic properties
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