Citation: LI Yue-Jun, CAO Tie-Ping, ZHAO Yan-Hui, SUN Da-Wei, WANG Xia. Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(8): 1371-1378. doi: 10.11862/CJIC.2019.187 shu

Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity

LI Yue-Jun ¹ ,
CAO Tie-Ping ^1,, ,
ZHAO Yan-Hui ¹ ,
SUN Da-Wei ^1,2 ,
WANG Xia ¹

1.
College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: CAO Tie-Ping, bcctp2008@163.com
Received Date: 16 March 2019
Revised Date: 8 June 2019

Figures(10)

By employing electrospun TiO₂ nanofiber as substrate, Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composite fibers were prepared via one-step hydrothermal method. The composition, morphology and optical properties were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), high-resolution transmission electron microscope (HRTEM), ultraviolet-visible diffuse reflection spectra (UV-Vis DRS) and photoluminescence spectroscopy (PL) analysis. The photocatalytic water splitting for hydrogen evolution was investigated over Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composite fibers with triethanolamine as the donor residue. The results showed that the Bi nanoparticles were generated onto Bi₂Sn₂O₇ nanoparticle via the in situ reduction of Bi³⁺ by glucose, meanwhile grew on the TiO₂ nanofibers surface. The enhanced photocatalytic activity of the Bi@Bi₂Sn₂O₇/TiO₂ plasmonic composites fibers can be further improved mainly attributed to the formation of high-quality p-n heterojunctions between Bi₂Sn₂O₇ and titanium dioxide, the plasma resonance effect of metal bismuth, and the synergistic effect of plasma resonance effect and p-n heterojunction. The corresponding H₂ production rate was 7.26 mmol·h^-1·g^-1.
- composite fibers,
- plasma,
- photocatalysis,
- hydrogen generation
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Preparation of Bi@Bi₂Sn₂O₇/TiO₂ Plasmonic Composite Fibers with Enhanced Photocatalytic Hydrogen Generation Activity