Citation: GOU Lei, ZHAO Shao-Pan, LIU Peng-Gang, YANG Jiang-Fan, FAN Xiao-Yong, LI Dong-Lin. Metal-Organic Framework Derived Co₃O₄/C Composite as High-Performance Anode Material for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1834-1842. doi: 10.11862/CJIC.2019.182 shu

Metal-Organic Framework Derived Co₃O₄/C Composite as High-Performance Anode Material for Lithium-Ion Batteries

Institute of New Energy Materials and Device, School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China

Corresponding author: GOU Lei, leigou@chd.edu.cn LI Dong-Lin, dlli@chd.edu.cn
Received Date: 23 April 2019
Revised Date: 6 June 2019

Figures(8)

In order to overcome the disadvantages of the low electrical conductivity and poor cycling stability of Co₃O₄ anode material, a Co₃O₄/C composite was obtained by the judicious selection of Co₂(NDC)₂DMF₂ (NDC=1,4-naphthalene dicarboxylate) as precursor through a two-step calcination process. The sample was characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The content of amorphous carbon in Co₃O₄/C was tested by thermogravimetric analysis (TGA). As anode material for lithium-ion batteries (LIBs), Co₃O₄/C material showed a high reversible specific capacity, remarkable cycling performance (the specific discharge capacity was stable at 1 000 mAh·g^-1 under the current density of 200 mA·g^-1 even after 200 cycles) and an excellent rate performance with high average discharge specific capacities of 1 076.3, 976.2, 872.9, 783.6 and 670.1 mAh·g^-1 at 100, 200, 500, 1 000 and 2 000 mA·g^-1, respectively. The excellent electrochemical performance was attributed to the amorphous carbon derived from the organic ligand, which served as conductive path for easy electric charge transfer and buffer layer to slow down the volumetric stresses.
- electrochemistry,
- lithium-ion battery,
- anode,
- composite,
- Co₃O₄,
- MOF
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Metal-Organic Framework Derived Co₃O₄/C Composite as High-Performance Anode Material for Lithium-Ion Batteries