Citation: TANG Long, YIN Si-Yu, WANG Ying-Lu, SHI De-Qian, HOU Xiang-Yang, WANG Xiao, WANG Ji-Jiang. Syntheses, Structures and Properties of Four Transition Metal Complexes with 2, 4-Oxybis(benzoic acid) and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1728-1736. doi: 10.11862/CJIC.2019.170 shu

Syntheses, Structures and Properties of Four Transition Metal Complexes with 2, 4-Oxybis(benzoic acid) and N-Donor Ligands

Yan'an University Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: TANG Long, ydtangl@126.com WANG Ji-Jiang, yadxwjj@126.com
Received Date: 18 April 2019
Revised Date: 5 May 2019

Figures(12)

Four transition metal coordination polymers {[Mn(2, 4-Hoba)₂(bipy)(H₂O)₂]·2H₂O}_n (1), [Mn(2, 4-oba)(phen)]_n (2), [Co(2, 4-oba)(bimyb)_0.5]_n (3) and[Ni(2, 4-oba)(bimyb)_0.5]_n (4) (2, 4-H₂oba=2, 4-oxybis(benzoic acid), bipy=4, 4'-bipyridine, phen=1, 10-phenanthroline, bimyb=1, 4-bis(imidazole-1-ylmethyl) benzene) were synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, IR spectroscopy and elemental analysis. Complex 1 is a 1D chain structure, which is extended to a 2D supramolecular architecture by O-H…O hydrogen bonding. Complex 2 shows a 1D wavy chain structure, which is expanded to a 2D wavelike network through aromatic π-π stacking interactions. Complexes 3 and 4 are 2D layer structures produced by ligands bridging binuclear paddle-wheel units. The magnetic properties of 2~4 have also been investigated, and the exchange conpling constants were -0.79, -8.97 and -11.42 cm^-1, respectively. According to the crystal structures, the magnetic coupling behavior of complexes 2~4 were studied by using hybrid DFT-BS method, and the result reveals that the calculated exchange coupling constants (J) are in good agreement with the experimental data.
- coordination polymers,
- crystal structure,
- magnetic behavior,
- density functional theory
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