Citation: Qi QI, LI Xing. Highly Selective Recognition to Cu²⁺ Based on Fluorinated Calix[4]arene Derivatives in Cone Conformation[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1301-1311. doi: 10.11862/CJIC.2019.160 shu

Highly Selective Recognition to Cu²⁺ Based on Fluorinated Calix[4]arene Derivatives in Cone Conformation

Qi QI ,
LI Xing ^,

Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Corresponding author: LI Xing, lixing@nbu.edu.cn; lix905@126.com
Received Date: 1 March 2019
Revised Date: 13 May 2019

Figures(19)

The fluorine derivatives of calix[4]arene, C₆₄H₅₂F₁₂O₄ (1), C₆₀H₅₂F₄O₄ (2), C₆₈H₄₈F₂₄O₄ (3), were synthesized, and their cone conformations were proved by single crystal X-ray diffraction and ¹H NMR spectroscopy. Their recognition behaviors were evaluated towards a variety of metal ions in mixed solvent. The UV-Vis absorption and fluorescence spectroscopy were measured and confirmed that copper ions resulted in fluorescence quenching of compounds 1~3, while other ions such as Na⁺, K⁺, Cs⁺, Mg²⁺, Ca²⁺, Ba²⁺, Fe³⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺ exerted hardly significant impact on the UV-Vis absorption and fluorescence intensity of 1~3, exhibiting high selectivity of compounds 1~3 to copper ions.
- calix[4]arene,
- recognition,
- selectivity,
- fluorinated derivatives
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Highly Selective Recognition to Cu2+ Based on Fluorinated Calix[4]arene Derivatives in Cone Conformation

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通讯作者: 陈斌, bchen63@163.com

Highly Selective Recognition to Cu²⁺ Based on Fluorinated Calix[4]arene Derivatives in Cone Conformation