Citation: SHEN Xian-Rong, MENG Yue, XIA Sheng-Jie. Water Gas Shift Reaction Catalyzed by AuCu Alloy Nanoparticles Supported on Layered Double Hydroxides: Catalytic Performance and Structural Composition[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1239-1247. doi: 10.11862/CJIC.2019.159 shu

Water Gas Shift Reaction Catalyzed by AuCu Alloy Nanoparticles Supported on Layered Double Hydroxides: Catalytic Performance and Structural Composition

1.
School of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu, Anhui 241000, China
2.
School of Life Sciences, Huzhou University, Huzhou, Zhejiang 313000, China
3.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: XIA Sheng-Jie, xiasj@zjut.edu.cn
Received Date: 30 March 2019
Revised Date: 15 May 2019

Figures(5)

Au nanoparticles supported on layered double hydroxides (Au/LDHs) and AuCu alloy nanoparticles supported on layered double hydroxides (AuCu/LDHs) based on ZnAl layered double hydroxides (ZnAl-LDHs) were synthesized and used for catalyzing water gas shift reaction (WGSR). The structure and composition of Au/LDHs and AuCu/LDHs was characterized and confirmed by using X-ray powder diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and scanning and transmission electron microscope (STEM). The effect of different molar ratios of Au and Cu (n_Au:n_Cu) for AuCu/LDHs onto the catalytic performance of WGSR was investigated and compared with the activity from Au/LDHs. It indicates that Au/LDHs has obviously higher activity compared to plain LDHs, while, AuCu alloy supporting can further largely enhance the catalytic activity for WGSR. Au₂Cu₁/LDHs (n_Au:n_Cu=2:1) exhibited the best catalytic efficiency:activity was 207.1 μmol·g_cat^-1·s^-1, TOF was 1.79 s^-1, and activity energy was 31.1 kJ·mol^-1. The effect of n_Au:n_Cu onto the Au particle size, Au dispersity, coverage degree of Au, and catalytic activity was discussed based on the comparison of physicochemical properties for different catalysts. The active species of Au/LDHs and AuCu/LDHs with different n_Au:n_Cu were analyzed and compared by X-ray photoelectron spectrometry (XPS). It was found that the introduction of the secondary element increased the percentage of Au^δ+ (Au₂Cu₁/LDHs had the highest Au^δ+ content), which maybe resulted in the enhancement of WGSR activity.
- AuCu alloy,
- supporting,
- layered double hydroxides,
- water gas shift reaction,
- catalyst composition,
- reaction activity
1. [1]
  Bobadilla L F, Penkova A, lvarez A, et al. Appl. Catal. A, 2015, 492:38-47 doi: 10.1016/j.apcata.2014.12.029
2. [2]
  Li Z, He T, Matsumura D, et al. ACS Catal., 2017, 7(10):6762-6769 doi: 10.1021/acscatal.7b01790
3. [3]
  Sivagurunathan P, Kumar G, Bakonyi P, et al. Int. J. Hydrogen Energy, 2016, 41(6):3820-3836 doi: 10.1016/j.ijhydene.2015.12.081
4. [4]
  Zhao Z J, Li Z L, Cui Y R, et al. J. Catal., 2017, 345:157-169 doi: 10.1016/j.jcat.2016.11.008
5. [5]
  WU Kai. Acta Phys.-Chim. Sin., 2018, 34(1):3-4
6. [6]
  Yang M, Li S, Wang Y, et al. Science, 2014, 346:1498-1501 doi: 10.1126/science.1260526
7. [7]
  Devaiah D, Smirniotis P G. Ind. Eng. Chem. Res., 2017, 56(7):1772-1781 doi: 10.1021/acs.iecr.6b04707
8. [8]
  Zhu M H, Wachs I E. ACS Catal., 2016, 6(2):722-732
9. [9]
  Pal D B, Chand R, Upadhyay S N, et al. Renewable Sustainable Energy Rev., 2018, 93:549-565 doi: 10.1016/j.rser.2018.05.003
10. [10]
  Wijayapala R, Yu F, Pittman C U, et al. Appl. Catal. A, 2014, 480:93-99 doi: 10.1016/j.apcata.2014.04.044
11. [11]
  Tang Q L, Duan X X, Zhang T T, et al. J. Phys. Chem. C, 2016, 120(44):25351-25360 doi: 10.1021/acs.jpcc.6b07050
12. [12]
  González-Castao M, Reina T R, Ivanova S, et al. Appl. Catal. B, 2016, 185:337-343 doi: 10.1016/j.apcatb.2015.12.032
13. [13]
  Rodriguez J A, Senanayake S D, Stacchiola D, et al. Acc. Chem. Res., 2014, 47(3):773-782 doi: 10.1021/ar400182c
14. [14]
  Abdel-Mageed A M, Kucerova G, Bansmann J, et al. ACS Catal., 2017, 7(10):6471-6484 doi: 10.1021/acscatal.7b01563
15. [15]
  Yao S Y, Zhang X, Zhou W, et al. Science, 2017, 357(6349):389-393 doi: 10.1126/science.aah4321
16. [16]
  GU Yan, LIU Guan-Ting, ZOU Cheng-Heng, et al. Chinese J. Inorg. Chem., 2017, 33(5):787-795
17. [17]
  Gamboa-Rosales N K, Ayastuy J L, Gutiérrez-Ortiz M A. Int. J. Hydrogen Energy, 2016, 41(42):19408-19417 doi: 10.1016/j.ijhydene.2016.05.237
18. [18]
  Nguyen-Phan T D, Baber A E, Rodriguez J A, et al. Appl. Catal. A, 2016, 518:18-47 doi: 10.1016/j.apcata.2015.12.012
19. [19]
  Flytzani-Stephanopoulos M. Acc. Chem. Res., 2014, 47(3):783-792 doi: 10.1021/ar4001845
20. [20]
  Carter J H, Althahban S, Nowicka E, et al. ACS Catal., 2016, 6(10):6623-6633 doi: 10.1021/acscatal.6b01275
21. [21]
  Xia S J, Shao M M, Zhou X B, et al. Phys. Chem. Chem. Phys., 2015, 17(40):26690-26702 doi: 10.1039/C5CP04125B
22. [22]
  Xia S J, Meng Y, Zhou X B, et al. Appl. Catal. B, 2016, 187:122-133 doi: 10.1016/j.apcatb.2016.01.027
23. [23]
  Xia S J, Zhang X F, Zhou X B, et al. Appl. Catal. B, 2017, 214:78-88 doi: 10.1016/j.apcatb.2017.05.033
24. [24]
  Hao C H, Guo X N, Pan Y T, et al. J. Am. Chem. Soc., 2016, 138:9361-9364 doi: 10.1021/jacs.6b04175
25. [25]
  Shi Y, Yang H M, Zhao X G, et al. Catal. Commun., 2012, 18:142-146 doi: 10.1016/j.catcom.2011.12.003
26. [26]
  Iqbal K, Iqbal A, Kirillov A M, et al. J. Mater. Chem. A, 2017, 5:6716-6724 doi: 10.1039/C6TA10880F
27. [27]
  Dutta S, Ray C, Negishi Y, et al. ACS Appl. Mater. Interfaces, 2017, 9(9):8134-8141 doi: 10.1021/acsami.7b00030
28. [28]
  Fang L, Luo W, Meng Y, et al. J. Phys. Chem. C, 2018, 122:17358-17369 doi: 10.1021/acs.jpcc.8b05463
29. [29]
  Liu Y, Wang N Y, Pan J H, et al. J. Am. Chem. Soc., 2014, 136(41):14353-14356 doi: 10.1021/ja507408s
30. [30]
  Mikami G, Grosu F, Kawamura S, et al. Appl. Catal. B, 2016, 199:260-271 doi: 10.1016/j.apcatb.2016.06.031
31. [31]
  Leandro S R, Mourato A C, Lapinska U, et al. J. Catal., 2018, 358:187-198 doi: 10.1016/j.jcat.2017.12.014
32. [32]
  Fu S F, Zheng Y, Zhou X B, et al. J. Hazard. Mater., 2019, 363:41-54 doi: 10.1016/j.jhazmat.2018.10.009
33. [33]
  Jin X J, Taniguchi K, Yamaguchi K, et al. Chem. Sci., 2016, 7(8):5371-5383 doi: 10.1039/C6SC00874G
34. [34]
  Zhang G H, Zhang X F, Meng Y, et al. J. Mater. Chem. A, 2018, 6:15839-15852 doi: 10.1039/C8TA05383A
35. [35]
  Zhang X F, Wang L W, Zhou X B, et al. ACS Sustainable Chem. Eng., 2018, 6:13395-13407 doi: 10.1021/acssuschemeng.8b03186
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