Citation: LIU Ling-Zhi, YU Meng, LI Xiao-Yan, KANG Quan-Peng, DONG Wen-Kui. Syntheses, Structures, Hirshfeld Analyses and Fluorescent Properties of Two Ni(Ⅱ) and Zn(Ⅱ) Complexes Constructed From a Bis(salamo)-like Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1283-1294. doi: 10.11862/CJIC.2019.158 shu

Syntheses, Structures, Hirshfeld Analyses and Fluorescent Properties of Two Ni(Ⅱ) and Zn(Ⅱ) Complexes Constructed From a Bis(salamo)-like Ligand

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 20 January 2019
Revised Date: 29 April 2019

Figures(11)

Two new homo-trinuclear Ni(Ⅱ) and Zn(Ⅱ) complexes, [Ni₃(L)(μ-OAc)₂(CH₃OH)₃]·CH₃OH·0.25CHCl₃ (1) and[Zn₃(L)(μ-OAc)₂(CH₃OH) (H₂O)]·2CH₃OH (2) with a newly synthesized C-type bis(salamo)-like ligand H₄L have been prepared and structurally characterized. The structures of complexes 1 and 2 were fully characterized by elemental analyses, FT-IR, UV-visible spectroscopy, single crystal X-ray crystallography, thermal analyses (TGA) and Hirshfeld surfaces analyses, and their luminescence properties were also discussed. The X-ray crystallography analyses demonstrated that complex 1 is an asymmetric trinuclear structure, and all Ni(Ⅱ) ions are hexa-coordinated, forming distorted octahedral geometries. Meanwhile, complex 2 is a symmetric trinuclear structure, the central Zn2 ion is hexa-coordinated and possesses a distorted octahedral coordination geometry. However, the terminal Zn1 and Zn1#1 ions are both penta-coordinated environments and adopt distorted trigonal bipyramidal geometries. In addition, 3D supramolecular architectures of complexes 1 and 2 were formed by hydrogen bonding and C-H…π interactions. Most importantly, the fluorescent property of complex 2 is totally different from that of complex 2.
- bis(salamo)-like ligand,
- complex,
- synthesis,
- Hirshfeld analysis,
- fluorescence property
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