Citation: WANG Yi, SHEN Qian-Qian, GUAN Rong-Feng, ZHAO Bin, XUE Jin-Bo, JIA Hu-Sheng, XU Bing-She. Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1221-1229. doi: 10.11862/CJIC.2019.153 shu

Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction

WANG Yi ^1,2 ,
SHEN Qian-Qian ¹ ,
GUAN Rong-Feng ³ ,
ZHAO Bin ^1,4 ,
XUE Jin-Bo ^1,, ,
JIA Hu-Sheng ^1,2,, ,
XU Bing-She ¹

1.
Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China
2.
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
3.
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
4.
State Key Laboratory of Fluid Power and Mechatronic Systems, Zhejiang University, Hangzhou 310027, China

Corresponding author: XUE Jin-Bo, xuejinbo@tyut.edu.cn JIA Hu-Sheng, jia_husheng@126.com
Received Date: 2 March 2019
Revised Date: 25 April 2019

Figures(12)

TiO₂/CdSe heterojunction was synthesized by anodic oxidation method and electrochemical deposition method. Then dehydrated polyvinyl alcohol films were spin coated on TiO₂/CdSe films with the annealing process. The crystal structure, morphology, photoelectrochemical and photocatlytic properties of the samples were investigated by XRD, SEM, FTIR, UV-Vis, PL, electrochemical and rhodamine B (RhB) degradation test. The photo-corrosion resistance of the nanocomposites were also evaluated by measuring the concentration of Cd²⁺ produced in the RhB degradation process. The results show that TiO₂/CdSe/PVA nanocomposites possess more excellent photocatalytic activity and good stability and photo-corrosion resistant properties compared to TiO₂/CdSe under visible light irradiation. Meanwhile, PVA can restrain Cd²⁺ the secondary pollutants in photocatalytic reaction.
- TiO₂/CdSe heterojunction,
- PVA,
- photocatalyst,
- photo-corrosion
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Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO2/CdSe Heterojunction

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通讯作者: 陈斌, bchen63@163.com

Application and Mechanism of PVA in Improving Photocatalytic Activity and Photo-Corrosion Resistance of TiO₂/CdSe Heterojunction