Citation: HU Guo-Rong, HUANG Jin-Long, DU Ke, CAO Yan-Bing, PENG Zhong-Dong. Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1139-1147. doi: 10.11862/CJIC.2019.140 shu

Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery

School of Metallurgical and Environment, Central South University, Changsha 410083, China

Corresponding author: HU Guo-Rong, 499498080@163.com
Received Date: 30 November 2018
Revised Date: 20 April 2019

Figures(13)

Precursor[Ni_0.85Co_0.08Mn_0.07](OH)₂ with continuous concentration gradient change of metal elements were prepared by a continuous crystallization method. The new gradient composite Cathode material Li[Ni_0.85Co_0.08Mn_0.07]O₂ was synthesized by sintering the mixture of as-prepared precursor and LiOH·H₂O in O₂. X-ray diffraction results indicated a low degree of cationic miscibility and a better layered structure. Scanning electronic microscopy showed the gradient material had a perfect spherical morphology. Particle size distribution was relatively concentrated in 11.5~12 μm. The line scan test of elements on the cross section area of coating shell showed that the main elements of the materials changed gradiently. From the center to the outer surface, the content of nickel became lower, while that of cobalt and manganese were higher. The initial discharge capacity was 204.3 mAh·g^-1 at 0.1C rate between 2.8 and 4.3 V. At 1C rate, its capacity was 185.3 mAh·g^-1 and retained 164.7 mAh·g^-1 (89.17%) after 100 cycles. When cycled at 55℃, the capacity of 1C rate was 202.7 mAh·g^-1 and retained 85.84% after 100 cycles, indicating good electrochemical capacity and cycling stability.
- Li-ion battery,
- cathode,
- high capacity,
- Li[Ni_0.85Co_0.08Mn_0.07]O₂
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of High Capacity Gradient Cathode Material Li[Ni0.85Co0.08Mn0.07]O2 for Lithium Ion Battery

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通讯作者: 陈斌, bchen63@163.com

Synthesis of High Capacity Gradient Cathode Material Li[Ni_0.85Co_0.08Mn_0.07]O₂ for Lithium Ion Battery