Citation: GUO Shu-Wang, GAO Zhan-Yong, SONG Jin-Ling, BULIN Chao-Ke, ZHANG Bang-Wen. ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1195-1202. doi: 10.11862/CJIC.2019.131 shu

ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids

School of Materials and Metallurgy & Instrumental Analysis Center, Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China

Corresponding author: ZHANG Bang-Wen, bangwenz@126.com
Received Date: 27 January 2019
Revised Date: 18 April 2019

Figures(5)

An ultra-thin MoS₂/reduced graphene oxide (UT-MoS₂/rGO) catalyst was prepared by one-step hydrothermal method, in which H₃PO₄·12MoO₃ and C₃H₇NO₂S were used as precursors and rGO was used as the carbon source. The microstructure of the UT-MoS₂/rGO catalyst and its catalytic performance for hydrogen evolution reaction (HER) were studied. The results showed that UT-MoS₂/rGO hybrid exhibited excellent electrocatalytic properties due to rich active sites from UT-MoS₂, robust support of electrically conducting rGO and good bonding between UT-MoS₂ and rGO. The initial overpotential was -66 mV; the overpotential was -145 mV at a current density of -10 mA·cm^-2 with the Tafel slope of 42.9 mV·dec^-1; the AC impedance was 0.76 Ω; the catalytic activity maintained 98% after 1 000 cycles at 0.1 to 0.2 V.
- hydrothermal synthesis,
- MoS₂,
- graphene,
- electrocatalysis,
- hydrogen evolution reaction
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ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids