Citation: ZHAO Na, LI Yu, FENG An-Sheng, ZOU Xun-Zhong. Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(Ⅱ) and Nickel(Ⅱ) Coordination Polymers Constructed from Biphenyl-Type Tricarboxylic Acids[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1248-1254. doi: 10.11862/CJIC.2019.094 shu

Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(Ⅱ) and Nickel(Ⅱ) Coordination Polymers Constructed from Biphenyl-Type Tricarboxylic Acids

Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: LI Yu, liyuletter@163.com ZOU Xun-Zhong, 2017018009@gdip.edu.cn
Received Date: 10 January 2019
Revised Date: 1 March 2019

Figures(9)

Two 1D cobalt(Ⅱ) and 2D nickel(Ⅱ) coordination polymers, namely[Co(μ₂-H₂btc)₂(4, 4'-bipy)₂]_n (1) and {[Ni₃(μ₄-dppa)₂(H₂O)₆]·2H₂O}_n (2), have been constructed hydrothermally using H₃btc (H₃btc=biphenyl-2, 4, 4'-tricarboxylic acid), H₃dppa (H₃dppa=5-(3, 4-dicarboxylphenyl)picolinic acid), 4, 4'-bipy(4, 4'-bipy=4, 4'-bipyridine), and cobalt or nickel chlorides. Single-crystal X-ray diffraction analyses reveal that both compounds crystallize in the triclinic system, space group \begin{document}$ P\bar 1$\end{document}. Compound 1 has a 1D double-helix chain structure, which is assembled to a 3D supramolecular framework through O-H…O/N hydrogen bond. Compound 2 shows a 2D sheet based on 1D chain units. Moreover, 4, 4'-bipy can tune the structures of both coordination polymers by its coordination or template effect. Magnetic studies for compound 1 demonstrate a ferromagnetic coupling between the adjacent Co(Ⅱ) centers.
- coordination polymer,
- double-helix chain,
- template effect,
- tricarboxylic acid,
- magnetic properties
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