Citation: ZHAO Yi-Ming, YANG Ji-Kai, MA Fu-Zhe, CHEN Zhang-Xiao-Xiong, WEI Zi-Juan, ZHANG Yu-Fei, CHENG Ming, YANG Xue, XIAO Nan, WANG Guo-Zheng, WANG Xin, HUANG Ke-Ke. Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 613-620. doi: 10.11862/CJIC.2019.088 shu

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes

1.
School of Science, Changchun University of Science and Technology, Changchun 130022, China
2.
Department of Nephrology, The First Hospital of Jilin University, Changchun 130021, China
3.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Corresponding author: YANG Ji-Kai, jikaiyang0625@163.com MA Fu-Zhe, mafuzhe2002@163.com
Received Date: 15 October 2018
Revised Date: 5 March 2019

Figures(7)

n-Type porous silicon were prepared by metal-assisted chemical etching (MACE) and then the porous Si/TiO₂ nanowires photoanodes were prepared by hydrothermal synthesis. Samples were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results showed that the macrospore size of the porous Si increases from about 0.1 to 0.4 μm with the increasing of etching time. Porous Si/TiO₂ nanowires corresponded primarily to rutile phase and slight traces of anatase. The results showed that porous Si/TiO₂ nanowires sample with etching for 35 min had the highest anti-reflectivity the corresponding photoanode showed the best photocurrent (photocurrent density) under simulated solar light. In addition, the photoelectric catalysis results showed that porous Si/TiO₂ nanowires with etching for 35 min at 1.5 V showed the best catalytic activities, which is attributed to the anti-reflection, heterogeneous effect and window effect.
- silicon,
- hydrothermal synthesis,
- water splitting,
- photolysis
1. [1]
  Fujishima A, Honda K. Nature, 1972, 238(5385):37-38
2. [2]
  Kümmerer K. J. Environ. Manage., 2009, 90(8):2354-2366 doi: 10.1016/j.jenvman.2009.01.023
3. [3]
  Asahi R, Morikawa T, Ohwaki T, et al. Science, 2001, 293(5528):269-271 doi: 10.1126/science.1061051
4. [4]
  Liao J H, Shi L Y, Yuan S, et al. J. Phys. Chem. C, 2009, 113(43):18778-18783 doi: 10.1021/jp905720g
5. [5]
  Albu S P, Ghicov A, Macak J M, et al. Nano Lett., 2007, 7(5):1286-1289 doi: 10.1021/nl070264k
6. [6]
  Lee K, Kim D, Roy P, et al. J. Am. Chem. Soc., 2010, 132(5):1478-1479 doi: 10.1021/ja910045x
7. [7]
  Zhu K, Neale N R, Miedaner A, et al. Nano Lett., 2007, 7(1):69-74 doi: 10.1021/nl062000o
8. [8]
  Liu Z Y, Zhang X T, Nishimoto S, et al. J. Phys. Chem. C, 2008, 112(1):253-259 doi: 10.1021/jp0772732
9. [9]
  Baram N, Ein-Eli Y. J. Phys. Chem. C, 2010, 114(21):9781-9790 doi: 10.1021/jp911687w
10. [10]
  Hou Y, Li X Y, Zhao Q D, et al. Environ. Sci. Technol., 2010, 44(13):5098-5103 doi: 10.1021/es100004u
11. [11]
  CHEN Yi, SHI Li-Yi, YUAN Shuai. Journal of Inorganic Materials, 2009, 24(4):680-684
12. [12]
  Chen X, Mao S S. Chem. Rev., 2007, 107(7):2891-2959 doi: 10.1021/cr0500535
13. [13]
  Hoffmann M R, Martin S T, Choi W, et al. Chem. Rev., 1995, 95(1):69-96 doi: 10.1021/cr00033a004
14. [14]
  Endo M, Strano M S, Ajayan P M. Topics in Applied Physics: Vol.111. Jorio A. Ed., Berlin, Heidelberg: Springer, 2007: 13-62
15. [15]
  Peng K Q, Wang X, Lee S T. Appl. Phys. Lett., 2008, 92(16):163103 doi: 10.1063/1.2909555
16. [16]
  Goodey A P, Eichfeld S M, Lew K K, et al. J. Am. Chem. Soc., 2007, 129(41):12344-12345 doi: 10.1021/ja073125d
17. [17]
  Nakato Y, Ueda T, Egi Y, et al. J. Electrochem. Soc., 1987, 134(2):353-358 doi: 10.1149/1.2100459
18. [18]
  Mills A, Davies R H, Worsley D. Chem. Soc. Rev., 1993, 22(6):417-425 doi: 10.1039/cs9932200417
19. [19]
  Garnett E C, Yang P. J. Am. Chem. Soc., 2008, 130(29):9224-9225 doi: 10.1021/ja8032907
20. [20]
  Li Y, Qian F, Xiang J, et al. Mater. Today, 2006, 9(10):18-27 doi: 10.1016/S1369-7021(06)71650-9
21. [21]
  Liu Y S, Ji G B, Wang J Y, et al. Nanoscale Res. Lett., 2012, 7(1):663 doi: 10.1186/1556-276X-7-663
22. [22]
  Goodey A P, Eichfeld S M, Lew K K, et al. J. Am. Chem. Soc., 2007, 129(41):12344-12345 doi: 10.1021/ja073125d
23. [23]
  Angelome P C, Andrini L, Calvo M E, et al. J. Phys. Chem. C, 2007, 111(29):10886-10893 doi: 10.1021/jp069020z
24. [24]
  Liu Y J, Szeifert J M, Feckl J M, et al. ACS Nano, 2010, 4(9):5373-5381 doi: 10.1021/nn100785j
25. [25]
  YU Li-Sheng. Physics of Semiconductor Heterojun-ctions. 2nd Ed.. Beijing:Science Press, 2006.
26. [26]
  Yu H T, Chen S, Quan X, et al. Appl. Catal. B, 2009, 90(1/2):242-248
27. [27]
  Hwang Y J, Boukai A, Yang P D. Nano Lett., 2008, 9(1):410-415
28. [28]
  Shi J, Hara Y, Sun C L, et al. Nano Lett., 2011, 11(8):3413-3419 doi: 10.1021/nl201823u
29. [29]
  Noh S Y, Sun K, Choi C, et al. Nano Energy, 2013, 2(3):351-360 doi: 10.1016/j.nanoen.2012.10.010
30. [30]
  KOU Yan-Qiang, YANG Ji-Kai, ZHU Ling-Xi, et al. Chem. J. Chinese Universities, 2015, 36(12):2485-2490 doi: 10.7503/cjcu20150378
31. [31]
  Peng K Q, Yan Y J, Gao S P, et al. Adv. Funct. Mater., 2003, 13(2):127-132 doi: 10.1002/adfm.200390018
32. [32]
  Huang Z P, Shimizu T, Senz S, et al. J. Phys. Chem. C, 2010, 114(24):10683-10690 doi: 10.1021/jp911121q
33. [33]
  Tsujino K, Matsumura M. Adv. Mater., 2005, 17(8):1045-1047 doi: 10.1002/(ISSN)1521-4095
34. [34]
  Xia W W, Zhu J, Wang H B, et al. CrystEngComm, 2014, 16(20):4289-4297 doi: 10.1039/C4CE00006D
35. [35]
  M T McDowell, M F Lichterman, A I Carim, et al. ACS Appl. Mater. Interfaces, 2015, 7(28):15189-15199 doi: 10.1021/acsami.5b00379
36. [36]
  Huang Z P, Geyer N, Werner P, et al. Adv. Mater., 2011, 23(2):285-308 doi: 10.1002/adma.v23.2
37. [37]
  Vazsonyi E, De Clercq K, Einhaus R, et al. Sol. Energy Mater. Sol. Cells, 1999, 57(2):179-188 doi: 10.1016/S0927-0248(98)00180-9
38. [38]
  Shankar K, Mor G K, Prakasam H E, et al. Nanotechnology, 2007, 18(6):065707 doi: 10.1088/0957-4484/18/6/065707
39. [39]
  Hinckley S, McCann J F, Haneman D. Solar Cells, 1986, 17(2/3):317-342
40. [40]
  Yu H T, Chen S, Quan X, et al. Appl. Catal. B, 2009, 90(1/2):242-248
41. [41]
  Yan J A, Yang L, Chou M Y. Phys. Rev. B, 2007, 76(11):115319 doi: 10.1103/PhysRevB.76.115319
42. [42]
  Cserveny S I. Int. J. Electron., 1968, 25(1):65-80 doi: 10.1080/00207216808938067
43. [43]
  Fulton C C, Lucovsky G, Nemanich R J. Appl. Phys. Lett., 2004, 84(4):580-582 doi: 10.1063/1.1639944
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
3. [3]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
4. [4]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
5. [5]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
6. [6]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
7. [7]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
8. [8]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
9. [9]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
10. [10]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
13. [13]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
14. [14]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
15. [15]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
16. [16]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
17. [17]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
20. [20]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(721)
HTML views(212)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO2 Nanowires Photoanodes

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photoelectrochemical Catalytic Properties of Porous Silicon/TiO₂ Nanowires Photoanodes