Citation: XUE Wen-Zhao, ZHAO Xiao-Lei, YAN Xue-Xue, ZHANG Xue-Jie, WU Wei-Na, WANG Yuan, CHEN Zhong. Ga(Ⅲ) and In(Ⅲ) Complexes with 3-Ethyl- 2-acetylpyrazine N(4)-(p-Tolyl) thiosemicarbazone:Synthesis, Crystal Structure and DNA-Binding Activity[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 745-751. doi: 10.11862/CJIC.2019.085 shu

Ga(Ⅲ) and In(Ⅲ) Complexes with 3-Ethyl- 2-acetylpyrazine N(4)-(p-Tolyl) thiosemicarbazone:Synthesis, Crystal Structure and DNA-Binding Activity

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
School of Materials and Mechanical and Electrical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China

Corresponding author: ZHAO Xiao-Lei, zhaoxiaolei@hpu.edu.cn; chenzhonglzu@hotmail.com CHEN Zhong,
Received Date: 4 December 2018
Revised Date: 17 January 2019

Figures(4)

Two novel complexes, [Ga(L)₂]NO₃·4CH₃OH (1) and[In(L)₂]NO₃·1.75CH₃OH (2) based on HL (HL=3-ethyl-2-acetylpyrazine N(4)-(p-tolyl)thiosemicarbazone) were synthesized and characterized by X-ray diffraction analyses. Complexes 1 and 2 are isostructural and crystallize in the monoclinic system, space group P2₁/c with different crystal methanol molecules. The metal center in each complex is surrounded by two monoanionic L^- with[N₂S] donor set, thus giving a distorted octahedral coordination geometry. In addition, the fluorescence spectra indicate that the interactions of complexes with DNA are stronger than that of ligand HL.
- thiosemicarbazone,
- Ga(III),
- In(III),
- crystal structure,
- DNA-binding activity
1. [1]
  Almeida S M, Lafayette E A, Silva L P, et al. Int. J. Mol. Sci., 2015, 6:13023-13042
2. [2]
  Majid R, Hassan K. Coord. Chem. Rev., 2014, 280:203-253 doi: 10.1016/j.ccr.2014.06.007
3. [3]
  Zhang X M, Guo H, Li Z S, et al. Eur. J. Med. Chem., 2015, 101:419-430 doi: 10.1016/j.ejmech.2015.06.047
4. [4]
  Ivanovic I, Gligorijevic N, Arandelovic N, et al. Polyhedron, 2013, 61:112-118 doi: 10.1016/j.poly.2013.05.050
5. [5]
  Lobana T S, Sharma R, Bawa G. Coord. Chem. Rev., 2009, 253:977-1055 doi: 10.1016/j.ccr.2008.07.004
6. [6]
  Du X, Guo C, Hansall E. J. Med. Chem., 2002, 45:2695-2707 doi: 10.1021/jm010459j
7. [7]
  Lovejoy D B, Richardson D R. Blood, 2002, 100:666-676 doi: 10.1182/blood.V100.2.666
8. [8]
  Santos I G, Abram U, Alberto R, et al. Inorg. Chim. Acta, 2004, 43:1834-1836 doi: 10.1021/ic035367u
9. [9]
  Turk S R, Shipman C, Drach J C. J. Gen. Virol., 1986, 67:1625-1632 doi: 10.1099/0022-1317-67-8-1625
10. [10]
  Dilworth J R, Hueting R. Inorg. Chim. Acta, 2012, 389:3-15 doi: 10.1016/j.ica.2012.02.019
11. [11]
  Vonlanthen M, Finney N S. J. Org. Chem., 2013, 78:3980-3988 doi: 10.1021/jo4003129
12. [12]
  Lessa J A, Parrilha G L, Beraldo H. Inorg. Chim. Acta, 2012, 393:53-63 doi: 10.1016/j.ica.2012.06.003
13. [13]
  Gambino D, Fernández M, Santos D, et al. Polyhedron, 2011, 30:1360-1366 doi: 10.1016/j.poly.2011.02.037
14. [14]
  Abram S, Maichle-Mssmer C, Abram U. Polyhedron, 1998, 17:131-143 doi: 10.1016/S0277-5387(97)00240-4
15. [15]
  Kowol C R, Berger R, Eichinger R, et al. J. Med. Chem., 2007, 50:1254-1265 doi: 10.1021/jm0612618
16. [16]
  da Silva J G, Azzolini L S, Wardell S M S V, et al. Polyhedron, 2009, 28:2301-2305 doi: 10.1016/j.poly.2009.04.022
17. [17]
  Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
18. [18]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
19. [19]
  LI Xiao-Jing, MAO Pan-Dong, WU Wei-Na, et al. Chinese J. Inorg. Chem., 2017, 33:1257-1265 doi: 10.11862/CJIC.2017.151
20. [20]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination:Part B. 6th Ed. New York:Wiley, 2009:65
21. [21]
  LIN Long, LI Xian-Hong, ZHANG Bo, et al. Chinese J. Inorg. Chem., 2017, 33:143-148 doi: 10.11862/CJIC.2016.283
22. [22]
  MAO Pan-Dong, ZHAO Xiao-Lei, SHAO Zhi-Peng, et al. Chinese J. Inorg. Chem., 2017, 33:890-896 doi: 10.11862/CJIC.2017.109
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
5. [5]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
6. [6]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
7. [7]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
8. [8]
  Xinghui Yao , Zhouyu Wang , Da-Gang Yu . Sustainable electrosynthesis: Enantioselective electrochemical Rh(III)/chiral carboxylic acid-catalyzed oxidative CH cyclization coupled with hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(9): 109916-. doi: 10.1016/j.cclet.2024.109916
9. [9]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
13. [13]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
14. [14]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
15. [15]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
16. [16]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876
17. [17]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
18. [18]
  Chang Liu , Tao Wu , Lijiao Deng , Xuzi Li , Xin Fu , Shuzhen Liao , Wenjie Ma , Guoqiang Zou , Hai Yang . Programmed DNA walkers for biosensors. Chinese Chemical Letters, 2024, 35(9): 109307-. doi: 10.1016/j.cclet.2023.109307
19. [19]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(265)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142