Eu3+/Tb3+-Doped Silica Nanoparticles with Controllable Structure, Composition and Fluorescent Properties
- Corresponding author: TAO Ke, ktao@sjtu.edu.cn
Citation: DENG Jie, LI Hai-Feng, LIU Yan, TANG Na, SUN Kang, TAO Ke. Eu3+/Tb3+-Doped Silica Nanoparticles with Controllable Structure, Composition and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 393-402. doi: 10.11862/CJIC.2019.068
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Excitation (a) and emission spectrum (c) of APTES-DTPA-PABA-Tb3+, λem=547 nm, λex=300 nm; Excitation (b) and emission spectrum (d) of APTES-DTPA-PABA-Eu3+, λem=617 nm, λex=308 nm
Inset of (d): FSNPs in aqueous solution under irradiation of 254 nm Hg lamp
TEM images of FSNPs prepared with (a~d) different water-to-surfactant molar ratios (R=7.9, 10.0, 12.1, 14.2), and (e~j) different APTES-DTPA-PTA-Eu3+ concentrations (10.8, 21.6, 43.2, 64.8, 108.0, 172.8 mmol·L-1)
DTPA-PTA-Eu3+ concentration: 27.6 mmol·L-1 (a) and 110.7 mmol·L-1 (b)
Sensitizer: Cm120, PTA, PABA; Ln3+: Eu3+, Tb3+
(a) Pure Tb3+, (b) nTb3+: nEu3+=3: 1, (c) nTb3+: nEu3+=1: 1, (d) nTb3+: nEu3+=1: 3, (e) Pure Eu3+; Inset: corresponding photographs of FSNPs in aqueous solution under irradiation of a 254 nm Hg lamp
Eu3+ loading amount: 0.92% (w/w) (black line), 5.45% (w/w) (red line) and 6.50% (w/w) (blue line); Inset: emission intensity of FSNPs at 617 nm with different Eu3+ loading amounts