Citation: LU Yan-Lei, ZHU Ning, ZHAO Yu-Meng, LIN Sen, KUANG Xiao-Nan, LI Zhong-Feng, XIN Xiu-Lan, YANG Yu-Ping, JIN Qiong-Hua, ZHANG Jiang-Wei. Syntheses, Structural Characterizations and Spectroscopic Properties of Two Copper(Ⅰ) Complexes Based on Diphosphine Ligands and[2, 3-f]pyrazino[1, 10]phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 720-728. doi: 10.11862/CJIC.2019.059 shu

Syntheses, Structural Characterizations and Spectroscopic Properties of Two Copper(Ⅰ) Complexes Based on Diphosphine Ligands and[2, 3-f]pyrazino[1, 10]phenanthroline

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
State Key Laboratory of Catalysis & Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn; jwzhang@dicp.ac.cn ZHANG Jiang-Wei,
Received Date: 19 November 2018
Revised Date: 19 December 2018

Figures(10)

Two novel copper(Ⅰ) complexes[Cu(dppBz)(dpq)]ClO₄ (1) and[Cu(dppe)(dpq)]ClO₄ (2) (dppBz=1, 2-bis(diphenylphosphino)benzene, dppe=1, 2-bis(diphenylphosphino)ethene, dpq=[2, 3-f]pyrazino^{[1, 10]}phenanthroline) have been synthesized and characterized by X-ray diffraction, elemental analysis, infrared spectroscopy, absorption spectra, luminescent spectra, ¹H NMR, ³¹P NMR spectroscopy and terahertz (THz) time-domain absorption spectroscopy. The central Cu(Ⅰ) ion is chelated by a diimine ligand and a diphosphine ligand forming a distorted tetrahedron configuration for 1, and the configuration of 2 is similar to 1. The luminescent spectra of 2 indicated that the emission has metal-to-ligand charge transfer (MLCT) characteristics. The terahertz time-domain absorption spectroscopy analysis in a range of 0.2~2.8 THz showed that the absorption peaks at 0.40~0.90 THz are related to the coordination of the central Cu(Ⅰ).
- [2, 3-f]pyrazino[1, 10]phenanthroline,
- Cu(Ⅰ) complexes,
- fluorescence,
- terahertz (THz) time-domain absorption spectroscopy
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