Citation: CHEN Jin-Wei, LI Yu, ZOU Xun-Zhong, QIU Wen-Da, CHENG Xiao-Ling. Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Nickel(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Constructed from 5-Chloronicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 505-514. doi: 10.11862/CJIC.2019.048 shu

Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Nickel(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Constructed from 5-Chloronicotinic Acid

1.
School of Light Chemical Engineering, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
3.
School of Chemical Engineering and Light Industry, Guangdong University of Techlonogy, Guangzhou 510006, China

Corresponding author: LI Yu, liyuletter@163.com CHENG Xiao-Ling, ggcxl@163.com
Received Date: 21 August 2018
Revised Date: 20 October 2018

Figures(14)

Two nickel(Ⅱ) and two zinc(Ⅱ) coordination polymers, namely {[Ni(μ-5-Clnic)(μ₃-5-Clnic)(μ-H₂O)_0.5]·1.5H₂O}_n (1), [Ni(5-Clnic)(μ-5-Clnic)(H₂biim)]_n (2), [Zn(5-Clnic)(μ-5-Clnic)(H₂biim)]_n (3) and {[Zn(5-Clnic)(μ-5-Clnic)(phen)]·2H₂O}_n (4), have been constructed hydrothermally using 5-ClnicH (5-ClnicH=5-chloronicotinic acid), phen (phen=1, 10-phenanthroline), H₂biim (H₂biim=2, 2'-biimidazole), and nickel or zinc chlorides. Single-crystal X-ray diffraction analyses revealed that four polymers crystallize in the monoclinic, orthorhombic (2, 3) or triclinic systems, space groups I2/a, Pbcn (2, 3) or P1. Polymer 1 possesses a 3D metal-organic framework based on dinuclear units. Polymers 2~4 show 1D chains, which are further extended into a 2D supramolecular network or 3D supramolecular framework through N-H…O hydrogen bonds or Cl…Cl interactions. Magnetic and luminescent properties of all compounds have been studied.
- coordination polymer,
- halogen bonding,
- 5-chloronicotinic acid,
- magnetic properties,
- luminescent properties
1. [1]
  Lu W G, Su C Y, Jiang L, et al. J. Am. Chem. Soc., 2006, 128:34-35 doi: 10.1021/ja0567337
2. [2]
  Zheng X D, Lu T B. CrystEngComm, 2010, 12:324-336 doi: 10.1039/B911991D
3. [3]
  Lee J Y, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38:1450-1459 doi: 10.1039/b807080f
4. [4]
  Cui Y J, Yue Y F, Chen B L. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
5. [5]
  Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009, 38:1477-1504 doi: 10.1039/b802426j
6. [6]
  Zhou Y L, Wu M C, Zeng M H, et al. Inorg. Chem., 2009, 48:10146-10150 doi: 10.1021/ic901085p
7. [7]
  Zhang L N, Zhang C, Zhang B, et al. CrystEngComm, 2015, 17:2837-2846 doi: 10.1039/C5CE00263J
8. [8]
  Du M, Li C P, Liu C S, et al. Coord. Chem. Rev., 2013, 257:1282-1305 doi: 10.1016/j.ccr.2012.10.002
9. [9]
  Chen X M, Tong M L. Acc. Chem. Res., 2007, 40:162-170 doi: 10.1021/ar068084p
10. [10]
  Singh R, Bharatdwaj P K. Cryst. Growth Des., 2013, 13:3722-3733 doi: 10.1021/cg400756z
11. [11]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
12. [12]
  Gu J Z, Cui Y H, Liang X X, et al. Cryst. Growth Des., 2016, 16:4658-4670 doi: 10.1021/acs.cgd.6b00735
13. [13]
  Gu J Z, Kirillov A M, Wu J, et al. CrystEngComm, 2013, 15:10287-10303 doi: 10.1039/c3ce41457d
14. [14]
  Wu Y P, Wu X Q, Wang J F, et al. Cryst. Growth Des., 2016, 16:2309-2316 doi: 10.1021/acs.cgd.6b00093
15. [15]
  Shao Y L, Cui Y H, Gu J Z, et al. CrystEngComm, 2016, 18:765-7783 doi: 10.1039/C5CE02254A
16. [16]
  Gao Z Q, Li H J, Gu J Z, et al. J. Solid State Chem., 2016, 241:121-130 doi: 10.1016/j.jssc.2016.05.034
17. [17]
  Cui Y H, Wu J, Kirillov A M, et al. RSC Adv., 2015, 5:10400-10411 doi: 10.1039/C4RA14534H
18. [18]
  Gu J Z, Cai Y, Liang X X, et al. CrystEngComm, 2018, 20:906-916 doi: 10.1039/C7CE02009K
19. [19]
  Spek A L. Acta Crystallogr. Sect. C:Struct. Chem., 2015, 71:9-18 doi: 10.1107/S2053229614024929
20. [20]
  Van de Sluis P, Spek A L. Acta Crystallogr. Sect. A:Found. Crystallogr., 1990, A46:194-201
21. [21]
  LIANG Li-Li, LIU Cong-Sen, ZONG Zhi-Hui, et al. Chinese J. Inorg. Chem., 2018, 34(7):1365-1372
22. [22]
  Bertani R, Sgarbossa P, Venzo A, et al. Coord. Chem. Rev., 2010, 254:677-695 doi: 10.1016/j.ccr.2009.09.035
23. [23]
  YAN Shi-Cheng, WU Da-Ling, ZHANG Min-Zhi, et al. Chinese J. Inorg. Chem., 2018, 34(6):1110-1120
24. [24]
  YANG Shi-Ying, CAI Hua, ZHANG Qi. Chinese J. Inorg. Chem., 2018, 34(1):179-186
25. [25]
  Thompson L K, Niel V, Grove H, et al. Polyhedron, 2004, 23:1175-1184 doi: 10.1016/j.poly.2004.01.022
26. [26]
  Mahata P, Natarajan S, Panissod P, et al. J. Am. Chem. Soc., 2009, 131:10140-10150 doi: 10.1021/ja9017539
27. [27]
  Kahn O. Molecular Magnetism. New York:VCH Publishers, 1993.
28. [28]
  Weng C H. Thesis for the Doctorate of Carnegie-Mellon University. 1968.
1. [1]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
2. [2]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
3. [3]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
4. [4]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
7. [7]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
10. [10]
  Haohao Sun , Wenxuan Wang , Yuli Xiong , Zelang Jian , Wen Chen . Boosting the electrochromic properties by large V₂O₅ nanobelts interlayer spacing tuned via PEDOT. Chinese Chemical Letters, 2024, 35(9): 109213-. doi: 10.1016/j.cclet.2023.109213
11. [11]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
12. [12]
  Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849
13. [13]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582
14. [14]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
15. [15]
  Yanbing Shen , Yuan Yuan , Yaxin Wang , Xiaonan Ma , Wensheng Yang , Yulan Chen . Dihydroanthracene bridged bis-naphthopyrans: A multimodal chromophore with mechano- and photo-chromic properties. Chinese Chemical Letters, 2024, 35(5): 108949-. doi: 10.1016/j.cclet.2023.108949
16. [16]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
17. [17]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
18. [18]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
19. [19]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
20. [20]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(243)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142