Citation: FENG Yong-Lan, KUANG Dai-Zhi, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Synthesis and Crystal Structure of Bis(4-(diethylamino)salicylaldehyde) Azodicarbonhydrazide Dibutyltin Complex with Aggregation Induced Emission Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 307-313. doi: 10.11862/CJIC.2019.043 shu

Synthesis and Crystal Structure of Bis(4-(diethylamino)salicylaldehyde) Azodicarbonhydrazide Dibutyltin Complex with Aggregation Induced Emission Properties

Key Laboratory of Functional Metal-organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: KUANG Dai-Zhi, hnkcq@qq.com
Received Date: 1 November 2018
Revised Date: 29 November 2018

Figures(5)

A novel seven-coordinated organotin complex[Sn(L)(n-butyl)₂]_n (T) based on bis(4-(diethylamino)salicylaldehyde) azodicarbonhydrazide(L) has been prepared by a one-pot reaction of carbohydrazide, 4-(diethylamino) salicylaldehyde and dibutyltin diacetate in methanol environments. The complex has been structurally characterized by elemental analysis, IR, (¹H, ¹³C, ¹¹⁹Sn) NMR spectra. The crystal of T belongs to monoclinic system and C2/c space group. The coordination around tin is distorted pentagonal bipyramid configuration by O, N atoms of L in the equatorial positions and the two butyl at the apices. A supramolecular structure of one-dimensional bands with a bamboo-row-like framework is formed by the bridging coordination of enol oxygen atoms. The complex had strong fluorescence emission in organic solvents, dimethyl formamide, tetrahydrofuran, ethanol, methanol and toluene, and in mixed solvents of organic solvent and water. When the volume fraction of water content is between 0 and 10%(V/V), the aggregation induced enhancement effect (AIEE) was good, and fluorescence quenching occured when the water content was more than 10%(V/V).
- bis(4-(diethylamino)salicylaldehyde) azodicarbonhydrazide,
- butyltin complex,
- crystal structure,
- fluorescence property
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