Citation: SU Qiong, ZHAO Qing, AN Xiao-Xin, WANG Yan-Bin, LI Xiao-Yan, DONG Wen-Kui. Syntheses, Crystal Structures, Hirshfeld Surface Analyses, Thermal and Fluorescent Properties of Cu(Ⅱ) and Ni(Ⅱ) Salamo-Type Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 524-536. doi: 10.11862/CJIC.2019.042 shu

Syntheses, Crystal Structures, Hirshfeld Surface Analyses, Thermal and Fluorescent Properties of Cu(Ⅱ) and Ni(Ⅱ) Salamo-Type Complexes

SU Qiong ¹ ,
ZHAO Qing ² ,
AN Xiao-Xin ² ,
WANG Yan-Bin ^1,, ,
LI Xiao-Yan ² ,
DONG Wen-Kui ^2,,

1.
Key Laboratory of Utility of Environmental Friendly Composite Materials and Biomass in Universities of Gansu Province, School of Chemical Engineering, Northwest Minzu University, Lanzhou 730030, China
2.
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: WANG Yan-Bin, ybwang@126.com DONG Wen-Kui, dongwk@126.com
Received Date: 29 September 2018
Revised Date: 27 November 2018

Figures(13)

Two new mononuclear Cu(Ⅱ) and trinuclear Ni(Ⅱ) Salamo-type complexes, namely[CuL] (1) and[Ni₃(L)₂(μ-OAc)₂(CH₃OH)₂]·CH₃OH (2), derived from a new containing coumarin-skeleton ligand H₂L were prepared and characterized by the means of elemental analyses, FT-IR, UV-Visible absorption spectra, single-crystal X-ray diffractions, fluorescence spectra, thermal (TG-DTA) properties and Hirshfeld surface analyses. The X-ray crystallography demonstrated that the Cu(Ⅱ) ion in the[N₂O₂] coordination sphere is four-coordinated forming a distorted square planar geometry in complex 1. Meanwhile, all Ni(Ⅱ) ions are six-coordinated and have the distorted octahedral coordination geometries in complex 2. The methanol molecule as a ligand participates in the coordination of complex 2. The strong supramolecular structures are formed via hydrogen bonding and C-H…π interactions in complexes 1 and 2. In addition, the thermal stabilities and Hirshfeld surface analyses of complexes 1 and 2 were analyzed in detail, and the fluorescent properties of complexes 1 and 2 were also investigated.
- Samalo ligand containing coumarin-skeleton,
- preparation,
- complex,
- fluorescence property,
- Hirshfeld surface analysis
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