Citation: ZHENG Xiao-Yuan, LIU Yang, QIN Liu-Lei, YU Fei-Fan, ZHU Chun-Li, LIU Zun-Qi. Synthesis, Structure and Dielectric Properties of Cyanide Cobalt(Ⅲ) Hydrogen-Bonding Cage-like Supramolecular Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 277-284. doi: 10.11862/CJIC.2019.036 shu

Synthesis, Structure and Dielectric Properties of Cyanide Cobalt(Ⅲ) Hydrogen-Bonding Cage-like Supramolecular Crystal

Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China

Corresponding author: LIU Yang, liuyangxj85@163.com LIU Zun-Qi, zunqi85@163.com
Received Date: 7 October 2018
Revised Date: 29 November 2018

Figures(10)

Using o-chloroaniline(o-CA), 18-crown-6 and cobalt cyanide as reactant, a small-molecule metal complex (H)_0.5(o-CAH)[Co(CN)₆]_0.5·(18-crown-6)_0.5·H₂O (1) was synthesized by evaporation in the mixed solution of methanol and water. The structure and electrical properties of 1 were characterized by single crystal X-ray diffraction, infrared spectroscopy, thermogravimetric analysis (TG) and dielectric measurements. The results showed that 1 crystalizes in the triclinic system with the space group P1 at low-temperature (100 K). The cell parameters are as follows:a=0.869 22(1) nm, b=0.964 09(12) nm, c=1.129 93(14) nm, α=77.894 0(10)°, β=78.877 0(10)°, γ=88.684 0(10)°. Single crystal X-ray diffraction show a three-dimensional cage-like structure through hydrogen bonds of cyanide cobalt, supramolecular cations and water molecules. When the temperature changed, the space between the cobalt atoms of the cage-like vertex showed significant stretching deformation, which resulted in the distinct dielectric anomaly observed around 260 K.
- crystal structure,
- hydrogen bond,
- metal organic,
- dielectric property
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