Citation: MEI Xue-Lan, DU Min-Jie, HU Peng, LI Zong-Qun. Syntheses, Structures and Magnetic Properties of Two Binuclear Lanthanide Complexes Bridged by Nitronyl Nitroxide Radical Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 323-328. doi: 10.11862/CJIC.2019.034 shu

Syntheses, Structures and Magnetic Properties of Two Binuclear Lanthanide Complexes Bridged by Nitronyl Nitroxide Radical Ligands

MEI Xue-Lan ^1,, ,
DU Min-Jie ² ,
HU Peng ³ ,
LI Zong-Qun ¹

1.
College of Materials Science and Chemical Engineering, Bengbu University, Bengbu, Anhui 233030, China
2.
Military Representative Bureau of Nanjing of the PLA Army, Hefei 230041, China
3.
College of Environment and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: MEI Xue-Lan, daluhuashu@126.com
Received Date: 30 August 2018
Revised Date: 26 November 2018

Figures(5)

The reaction of Ln(acac)₃·3H₂O with NIT-PhOH radical yielded two new Ln-radical complexes[Ln₂(acac)₄(NIT-PhO)₂] (Ln=Tb (1), Y (2); acac=acetylacetonato, NIT-PhOH=2-(2'-hydroxyphenyl)-4, 4, 5, 5-tetramethylimidazo-line-1-oxyl-3-oxide). Two complexes are isostructural and have binuclear structure in which two lanthanide ions are bridged by two radical ligands through their phenoxo-O atoms. DC magnetic susceptibility studies indicated that there exists weak antiferromagnetic interaction in complex 2.
- lanthanide complexes,
- crystal structure,
- magnetic properties,
- radical
1. [1]
  Hansen P, Lachowicz H K. Physics of Magnetic Materials. Singapore:World Scientific, 1985:158
2. [2]
  Liu K, Zhang X J, Meng X X, et al. Chem. Soc. Rev., 2016, 45(9):2423-2439 doi: 10.1039/C5CS00770D
3. [3]
  Zhe Y Z, Evangelisti M, Winpenny R E P. Angew. Chem. Int. Ed., 2011, 50(16):3692-3695 doi: 10.1002/anie.v50.16
4. [4]
  REN Min, ZHENG Li-Min. Acta Chim. Sinica, 2015, 73:1091-1113
5. [5]
  LI Dong-Ping, WANG Qian, XIE Yi-Bu, et al. Chinese J. Inorg. Chem., 2018, 34(8):1547-1554
6. [6]
  Cornia A, Fabretti A C, Pacchioni M, et al. Angew. Chem., Int. Ed., 2003, 42(14):1645-1648 doi: 10.1002/anie.200350981
7. [7]
  Guo F S, Day B M, Chen Y C, et al. Angew. Chem. Int. Ed., 2017, 56(38):11445-11449 doi: 10.1002/anie.v56.38
8. [8]
  Goodwin C A P, Ortu F, Reta D, et al. Nature, 2017, 548(7668):439-442 doi: 10.1038/nature23447
9. [9]
  Harriman K L M, Brosmer J L, Ungur L, et al. J. Am. Chem. Soc., 2017, 139(4):1420-1423 doi: 10.1021/jacs.6b12374
10. [10]
  Peng J B, Zhang Q C, Kong X J, et al. J. Am. Chem. Soc., 2012, 134(7):3314-3317 doi: 10.1021/ja209752z
11. [11]
  Song X Q, Liu P P, Liu Y A, et al. Dalton Trans., 2016, 45(19):8154-8163 doi: 10.1039/C6DT00212A
12. [12]
  Bernot K, Pointillart F, Rosa P, et al. Chem. Commun., 2010, 46(35):6458-6460 doi: 10.1039/c0cc00966k
13. [13]
  Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011, 133(36):14236-14239 doi: 10.1021/ja206286h
14. [14]
  Brian S D, Dimitris I A, Kuduva R V, et al. J. Am. Chem. Soc., 2018, 140(3):908-911 doi: 10.1021/jacs.7b12495
15. [15]
  HU Peng, GAO Yuan-Yuan, XIAO Feng-Yi, et al. Chinese J. Inorg. Chem., 2017, 33(1):33-40
16. [16]
  Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003, 125(29):8694-8695 doi: 10.1021/ja029629n
17. [17]
  Tang J K, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006, 45(11):1729-1733 doi: 10.1002/(ISSN)1521-3773
18. [18]
  Hewitt I J, Tang J K, Madhu N T, et al. Angew. Chem. Int. Ed., 2010, 49(36):6352-6356 doi: 10.1002/anie.201002691
19. [19]
  Huang G, Fernandez-Garcia G, Badiane I, et al. Chem. Eur. J., 2018, 24(27):6983-6991 doi: 10.1002/chem.v24.27
20. [20]
  Lescop C, Luneau D, Belorizky E, et al. Inorg. Chem., 1999, 38:5472 doi: 10.1021/ic990996i
21. [21]
  Tian H X, Wang X F, Mei X L, et al. Inorg. Chem., 2013, 8:1320-1325
22. [22]
  Sutter J P, Kahn M L, Golhen S, et al. Chem. Eur. J., 1998, 4(4):571-576
23. [23]
  Hu P, Zhu M, Mei X L, et al. Dalton Trans., 2012, 41:14651-14656 doi: 10.1039/c2dt31806g
24. [24]
  Caneschi A, Gatteschi D, Rey P. Prog. Inorg. Chem., 1991, 39:331-429
25. [25]
  Poneti G, Bernot K, Bogani L, et al. Chem. Commun., 2007, 18:1807-1809
26. [26]
  Lannes A, Intissar M, Suffren Y, et al. Inorg. Chem., 2014, 53(18):9548-9560 doi: 10.1021/ic500779y
27. [27]
  Bernot K, Pointillart F, Rosa P, et al. Chem. Commun., 2010, 46:6458-6460 doi: 10.1039/c0cc00966k
28. [28]
  Mei X L, Liu R N, Wang C, et al. Dalton Trans., 2012, 41:2904-2909 doi: 10.1039/c2dt11671e
29. [29]
  Mei X L, Wang X F, Wang J J, et al. New J. Chem., 2013, 37:3620-3626 doi: 10.1039/c3nj00739a
30. [30]
  Liu R N, Zhang C M, Li L C, et al. Dalton Trans., 2012, 41:12139-12144 doi: 10.1039/c2dt31310c
31. [31]
  Shinya K, Yasunori T, Yasuchika H, et al. Bull. Chem. Soc. Jpn., 2007, 80:1492-1503 doi: 10.1246/bcsj.80.1492
32. [32]
  Tretyakov E V, Eltsov I V, Fokin S V, et al. Polyhedron, 2003, 22:2499-2514 doi: 10.1016/S0277-5387(03)00228-6
33. [33]
  Kanda H, Narumi Y, Hosokoshi Y, et al. Inorg. Chim. Acta, 2004, 357:3125-3133 doi: 10.1016/j.ica.2004.03.017
34. [34]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
35. [35]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
36. [36]
  Lluncll M, Casanova D, Circra J, et al. SHAPE, Ver.2.1, University of Barcelona:Spain, Hebrew University of Jerusalem:Israel, 2005.
37. [37]
  Liu R N, Liu L, Fang D, et al. Z. Anorg. Allg. Chem., 2015, 641(3/4):728-731
38. [38]
  Benelli C, Caneschi A, Gatteschi D, et al. Inorg. Chem., 1993, 32(22):4797-4801 doi: 10.1021/ic00074a023
39. [39]
  Jung J, Puget M, Cador O, et al. Inorg. Chem., 2017, 56(12):6788-6801 doi: 10.1021/acs.inorgchem.6b02952
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
3. [3]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
4. [4]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
5. [5]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
6. [6]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
7. [7]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
8. [8]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
13. [13]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
14. [14]
  Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348
15. [15]
  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
16. [16]
  Jindian Duan , Xiaojuan Ding , Pui Ying Choy , Binyan Xu , Luchao Li , Hong Qin , Zheng Fang , Fuk Yee Kwong , Kai Guo . Oxidative spirolactonisation for modular access of γ-spirolactones via a radical tandem annulation pathway. Chinese Chemical Letters, 2024, 35(10): 109565-. doi: 10.1016/j.cclet.2024.109565
17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Jing-Qi Tao , Shuai Liu , Tian-Yu Zhang , Hong Xin , Xu Yang , Xin-Hua Duan , Li-Na Guo . Photoinduced copper-catalyzed alkoxyl radical-triggered ring-expansion/aminocarbonylation cascade. Chinese Chemical Letters, 2024, 35(6): 109263-. doi: 10.1016/j.cclet.2023.109263
20. [20]
  Wei Zhou , Xi Chen , Lin Lu , Xian-Rong Song , Mu-Jia Luo , Qiang Xiao . Recent advances in electrocatalytic generation of indole-derived radical cations and their applications in organic synthesis. Chinese Chemical Letters, 2024, 35(4): 108902-. doi: 10.1016/j.cclet.2023.108902

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(764)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142