Citation: BU Guan, SUN Jing, ZHOU Chen, YU Wen-Sheng, WANG Yuan, TANG Juan. Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)₃phen] and[Eu(PCBA)₃phen][J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 203-208. doi: 10.11862/CJIC.2019.029 shu

Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)₃phen] and[Eu(PCBA)₃phen]

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Changchun 130022, China

Corresponding author: SUN Jing, sj-cust@126.com ZHOU Chen, 59982153@qq.com
Received Date: 21 August 2018
Revised Date: 16 November 2018

Figures(6)

Europiumsesquioxide (Eu₂O₃), parachlorobenzoic-acid (PCBA), parabromobenzoic acid (PBrBA) and o-phenanthroline (phen) were used as raw materials to synthesize two kinds of probe molecules Eu(PCBA)₃phen and Eu(PBrBA)₃phen. And these two probe molecules were doped in the substrate of polymethyl methacrylate (MMA), benzoyl (BPO) peroxide as initiator, to prepare two kinds of temperature sensitive paints. The infrared spectrometer, ultraviolet spectrometer, scanning electron microscope and fluorescence spectrometer were utilized to analyze the structure, fluorescence properties, morphology and temperature sensitivity of the probes, respectively. Meanwhile the effects of different ligands on the fluorescence properties of the probe molecules and the relevant temperature sensitive paints were studied. The results showed that Eu³⁺ was coordinated with the main ligand of PCBA and PBrBA, respectively, and the second ligand phen was involved in the coordination, which confirms that two new complexes were synthesized. Both complexes emit characteristic fluorescence of Eu³⁺, and the ternary complex of phenanthroline europium with PBrBA as the main ligand has better fluorescent properties. Furthermore, the temperature sensitive paints based on these two probes both had temperature-quenching performance in a range of 50~90℃, and the temperature sensitive paint doped with Eu(PCBA)₃phen had better temperature sensitivity.
- temperature sensitive paint,
- fluorescent probes,
- polymers,
- halogenated benzoic acid,
- o-phenanthroline
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)3phen] and[Eu(PCBA)3phen]

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)₃phen] and[Eu(PCBA)₃phen]