Citation: LI Yun-Tao, QIU Shuo, DU Teng, Wei WEI, HAN Zhen-Bing, RUAN Fang-Yi, CAO Li-Hui. Decoration of Graphene Oxide Sheets with Luminescent Heteronuclear Rare-Earth Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 174-182. doi: 10.11862/CJIC.2019.016 shu

Decoration of Graphene Oxide Sheets with Luminescent Heteronuclear Rare-Earth Complexes

Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science and Technology, Xi'an 710021, China

Corresponding author: QIU Shuo, roseofsnow@163.com
Received Date: 26 September 2018
Revised Date: 13 November 2018

Fund Project: 国家自然科学基金青年项目 21701106国家自然科学基金青年项目(No.21701106)资助

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A novel high luminescent performance of graphene oxide-rare earth hybrid material was prepared using a noncovalent approach. Herein, a heteronuclear rare earth complex were revealed in which the benzoic acid (BA) and 1, 10-phenanthroline hydrate (Phen) coordinated with Sm³⁺ and Gd³⁺, which was used to functionalize graphene oxide sheets (GOSs). The as-prepared products were characterized via Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscope, fluorescence spectrometer, decay lifetime and thermogravimetric analysis. The hybrid materials exhibited strong luminescence intensity, long lifetime and good thermal stability. Besides, Gd³⁺ ions had a strong sensitizing effect on materials and played a significant role in improving the luminescence intensity. The presence of GOSs did not quench the fluorescence performance of hybrid materials. Moreover, their fluorescence properties of Sm³⁺ and Gd³⁺ with different molar ratios were also studied.
- graphene oxide,
- samarium,
- rare earths,
- luminescence
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