Citation: LI Yu, ZOU Xun-Zhong, QIU Wen-Da, ZHUANG Wen-Liu, ZHAO Na, CHENG Xiao-Ling. Syntheses, Crystal Structures, and Luminescent Properties of Three Cobalt(Ⅱ), Lead(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from Mixed Biphenyl Tricarboxylic Acid and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 329-336. doi: 10.11862/CJIC.2019.002 shu

Syntheses, Crystal Structures, and Luminescent Properties of Three Cobalt(Ⅱ), Lead(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from Mixed Biphenyl Tricarboxylic Acid and N-Donor Ligands

1.
Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: LI Yu, liyuletter@163.com CHENG Xiao-Ling, ggcxl@163.com
Received Date: 1 September 2018
Revised Date: 12 October 2018

Figures(9)

Zero-dimensional mononuclear cobalt(Ⅱ) complex, 1D lead(Ⅱ) and 1D zinc(Ⅱ) coordination polymers, namely[Co(Hbtc)(phen)₂(H₂O)]·3H₂O (1), [Pb(μ₃-Hbtc)(2, 2'-bipy)]_n (2) and {[Zn₃(μ₂-btc)₂(μ₂-H₂O)(2, 2'-bipy)₃(H₂O)₅]·8H₂O}_n (3), have been constructed hydrothermally using H₃btc (H₃btc=biphenyl-2, 4, 4'-tricarboxylic acid), phen (phen=1, 10-phenanthroline), 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and cobalt, lead or zinc chlorides. Single-crystal X-ray diffraction analyses revealed that three complexes crystallize in the orthorhombic or triclinic systems, space groups Pna2₁ or P1. Complex 1 has a discrete monomeric structure, which is assembled to a 3D supramolecular framework through O-H…O hydrogen bond. Complexes 2 and 3 show a 1D chain based on binuclear units. Luminescent properties of all complexes have been studied.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- luminescent properties
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沈阳化工大学材料科学与工程学院沈阳 110142