Citation: SU Peng-He, ZHEN Lu-An, CHEN Ya, LIU Xiao-Tong, ZHU Bao-Lin, ZHANG Shou-Min, HUANG Wei-Ping. Catalytic Performances for Hydroformylation of Cyclohexene of MgSNTs-Supported Amorphous Co-B Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2197-2204. doi: 10.11862/CJIC.2018.275
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Novel silicate nanotubes supported amorphous Co-B (Co-B/MgSNTs) were synthesized via a hydrothermal method followed by impregnation-chemical reduction processes. The catalysts were characterized with X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectrometer (XPS), atomic emission spectrometer (ICP) and brunauer-Emmett-Tellerv (BET) surface-area analyzers. The catalytic activity and recyclability of catalysts for hydroformylation of cyclohexene were evaluated. The conversion of cyclohexene over the catalysts is 75.8% and selectivity for aldehyde is 65.8%. The results indicate that Co-B nanoparticles were deposited on the inner and outer surface of MgSNTs, which had large specific surface area and high stability. Furthermore, the tubular structure of nanotubes could prevent nanoparticle from agglomeration. The catalyst used for 3 recycles shows good catalytic activity.
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Keywords:
- nanotubes,
- silicate,
- hydroformylation,
- cyclohexene
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