Citation: LIU Yuan-Yuan, LI Xin Shu, ZHANG Hui-Min, DING Bin. Three Polyoxometalate-Based Cu(Ⅱ) and Cu(Ⅰ) Coordination Polymers with Mono-and Bis-triazole Derivatives: Hydrothermal Assembly and Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2280-2290. doi: 10.11862/CJIC.2018.274 shu

Three Polyoxometalate-Based Cu(Ⅱ) and Cu(Ⅰ) Coordination Polymers with Mono-and Bis-triazole Derivatives: Hydrothermal Assembly and Photocatalytic Properties

LIU Yuan-Yuan ^1,2,, ,
LI Xin Shu ¹ ,
ZHANG Hui-Min ¹ ,
DING Bin ^1,2

1.
Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: LIU Yuan-Yuan, hxxylyy@mail.tjnu.edu.cn
Received Date: 6 August 2018
Revised Date: 26 September 2018

Figures(12)

Three novel polyoxometalate (POM)-based Cu(Ⅱ) and Cu(Ⅰ) hybrid materials with multi-dentate mono-and bis-triazole derivatives, namely {[Cu(L¹)₂(Mo₄O₁₃)]·2H₂O}_n (1), {[Cu_1.5(L²)(HL₂)(H₂O)(Mo₄O₁₃)]·2H₂O}_n (2), {[Cu₂(L₃)_1.5(Mo₄O₁₃)]·H₂O}_n (3) (L₁=4-pyridine-2-1, 2, 4-triazole, HL₂=3-(4H-1, 2, 4-triazol-4-yl) benzoic acid, L₃=trans-4, 4'-azo-1, 2, 4-triazole) have been designed and synthesized by hydrothermal method. The structures of 1~3 have been determined by single crystal X-ray diffraction, FT-IR infrared spectra and powder X-ray diffraction analyses. In 1, Mo₄O₁₃^2- anions and Cu(Ⅱ) centers are inter-linked by bidentate L₁, which are arranged into 2D POMs-based Cu(Ⅱ) hybrid metal-organic framework. In 2, Mo₄O₁₃^2- anions and Cu(Ⅱ) centers are inter-linked via bridging aqua atoms (O18), bi-dentate HL₂ and tri-dentate L₂^-, which are arranged into 3D POM-based Cu(Ⅱ) micro-porous metal-organic framework. In 3, L₃ ligands bridge neighboring Cu(Ⅰ) centers and Mo₄O₁₃^2- anions, which ultimately forms unique two-fold interpenetrating 3D POM-based Cu(Ⅰ) hybrid coordination framework. Photocatalytic activities for decomposition of different organic dyes of rhodamine B (RhB), methylene blue (MB) and methyl orange (MO) have been investigated for 1~3, indicating that 1~3 are good candidates for photocatalytic degradation of the organic dyes.
- triazole,
- Cu (Ⅱ),
- Cu (Ⅰ),
- polyoxometalate,
- photocatalytic
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