Citation: GUO Hu, LI Ling-Hui, WANG Tao, FAN Xiao-Li, SONG Li, GONG Hao, XIA Wei, JIANG Cheng, GAO Bin, HE Jian-Ping. Preparation and Catalytic Activity for Oxygen Reduction Reaction of Tungsten Nitirde-Tungsten/Nitrogen Doped Ordered Mesoporous Carbon[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2032-2040. doi: 10.11862/CJIC.2018.263 shu

Preparation and Catalytic Activity for Oxygen Reduction Reaction of Tungsten Nitirde-Tungsten/Nitrogen Doped Ordered Mesoporous Carbon

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: HE Jian-Ping, jianph@nuaa.edu.cn
Received Date: 18 July 2018
Revised Date: 17 September 2018

Figures(8)

Tungsten nitride-Tungsten/nitrogen doped ordered mesoporous carbon (WN/W-NOMC), as a non-precious-metal cathode catalyst for oxygen reduction reaction (ORR), was successfully synthesized through a soft-template method.The amount of nitrogen was adjusted by urea, and when the content of nitrogen was 7%(w/w), the obtained composite had highly ordered mesoporous structure, and its specific surface area reached to 835 m²·g^-1.Transmission electron microscope (TEM) shows that the catalytic particles were uniform supported on NOMC.ORR test was conducted in O₂-staturated 0.1 mol·L^-1 KOH solution, the oneset potential is 0.87 V (vs RHE) and the limiting current density is 4.49 mA·cm^-2.The transfer number of electron was 3.4, which was close to commercial 20%(w/w) Pt/C (3.8), indicated that WN-NOMC exhibited an approximate 4e^- transfer pathway during the ORR process.Though the catalytic activity is less than Pt/C, the excellent methanol tolerance and long-time electrochemical stability make WN-W/NOMC to be a potential electrode catalyst for ORR.
- tungsten nitride,
- electrocatalysis,
- ordered mesoporous carbon,
- oxygen reduction reaction,
- fuel cells
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