Citation: ZHANG Hong-Jia, CHANG Jian, JIA Hao-Ran, SUN Yin-Xia. Syntheses, Supramolecular Structures and Spectroscopic Properties of Cu(Ⅱ) and Ni(Ⅱ) Complexes with Schiff Base Containing Oxime Group[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2261-2270. doi: 10.11862/CJIC.2018.261 shu

Syntheses, Supramolecular Structures and Spectroscopic Properties of Cu(Ⅱ) and Ni(Ⅱ) Complexes with Schiff Base Containing Oxime Group

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: SUN Yin-Xia, sun_yinxia@163.com
Received Date: 25 July 2018
Revised Date: 23 August 2018

Figures(11)

Two Cu(Ⅱ) and Ni(Ⅱ) complexes, [Cu(L¹)₂]·(1, 4-dioxane) (1) (HL¹=8-(((4-(1-((benzyloxy) imino) ethyl) phenyl) imino) methyl)-7-hydroxy-4-methyl-2H-chromen-2-one) and[Ni(L²)₂] (2) (HLL²=1-(4-(((2-hydroxynaphthalen-1-yl) methylene) amino) phenyl) ethanone O-benzyloxime), have been synthesized and characterized by elemental analyses, IR spectra, UV-Vis spectra, fluorescence spectra and X-ray single crystal diffraction method. X-ray crystallographic analysis shows that the Cu(Ⅱ) and Ni(Ⅱ) ions are all four-coordinated in a trans-N₂O₂ slightly distorted square-planar geometry by two hydroxy O and two imine N atoms from two N, O-bidentate Schiff base ligands. Moreover, complex 1 links some other molecules into an infinite 3D supramolecular structure by intermolecular hydrogen bonds and π…π stacking interactions, while complex 2 forms 1D infinite chain via intermolecular π…π stacking interactions. Furthermore, the fluorescence property of HL¹, HLL² and their metal complexes 1 and 2 are discussed.
- Schiff base ligand,
- Cu (Ⅱ) and Ni (Ⅱ) complexes,
- supramolecular structure,
- fluorescence property
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