Citation: CHANG Jian, ZHANG Hong-Jia, JIA Hao-Ran, SUN Yin-Xia. Binuclear Nickel(Ⅱ) and Zinc(Ⅱ) Complexes Based on 2-Amino-3-hydroxy-pyridine Schiff Base: Syntheses, Supramolecular Structures and Spectral Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2097-2107. doi: 10.11862/CJIC.2018.256 shu

Binuclear Nickel(Ⅱ) and Zinc(Ⅱ) Complexes Based on 2-Amino-3-hydroxy-pyridine Schiff Base: Syntheses, Supramolecular Structures and Spectral Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: SUN Yin-Xia, sun_yinxia@163.com
Received Date: 14 July 2018
Revised Date: 11 September 2018

Figures(15)

Two 2-amino-3-hydroxy-pyridine Schiff base binuclear Ni(Ⅱ) and Zn(Ⅱ) complexes, [Ni(L¹)(DMF)]₂ (1) (H₂L¹=4-hydroxy-3-((3-hydroxy-pyridin-2-ylimino)-methyl)-chromen-2-one) and[Zn(L²)(H₂O)]₂·2DMF (2) (H₂L²=2-((3, 5-dibromo-2-hydroxy-benzylidene)-amino)-pyridin-3-ol) have been synthesized and characterized by elemental analyses, IR, UV-Vis, emission spectra and X-ray crystallography. X-ray crystallography analyses showed that complexes 1 and 2 all possess the binuclear structures, consisting of two metal ions, two ligand units and two coordinated solvent molecules, in which the difference is that complex 2 contains two solvent molecules. Complexes 1 and 2 crystallize in the monoclinic space group P2₁/c and the center Ni(Ⅱ) and Zn(Ⅱ) are all five-coordinated slightly distorted square pyramid geometry by four O atoms and one imine N atoms. Complex 1 (or 2) links some other molecules into an infinite 3D network supramolecular structure via intermolecular hydrogen bond, C-H…π or π…π stacking interactions. And the fluorescent properties of H₂L¹, H₂L² and their corresponding Ni(Ⅱ) and Zn(Ⅱ) complexes have been discussed. The ligands H₂L¹ and H₂L² exhibit blue emission with the maximum emission wavelength λ_em=457 and 473 nm, and complexes 1 and 2 show green emission with λ_em=543 and 538 nm.
- 2-amino-3-hydroxy-pyridine Schiff base,
- binuclear complex,
- supramolecular structure,
- fluorescence property
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