Citation: WANG Peng-Fei, WANG Li-Jun. Zn-Based MOF Containing Rod-Shaped Metal-Carboxylate/Hydroxyl SBU Exhibiting Afterglow Property at Low Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2254-2260. doi: 10.11862/CJIC.2018.246 shu

Zn-Based MOF Containing Rod-Shaped Metal-Carboxylate/Hydroxyl SBU Exhibiting Afterglow Property at Low Temperature

WANG Peng-Fei ^1,2,, ,
WANG Li-Jun ¹

1.
School of Chemistry and Material Engineering, Chizhou University, Chizhou, Anhui 247000, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com
Received Date: 22 July 2018
Revised Date: 13 August 2018

Figures(7)

A three-dimensional (3D) porous Zn(Ⅱ)-based framework, {[Zn₄(O-BTC)₂(H₂O)₅]·2DMF·0.5H₂O}_n (1), which is constructed from a multifunctional tricarboxylate ligand, 2-hydroxyl-1, 3, 5-benzenetricarboxylic acid (HO-H₃BTC) and Zn(Ⅱ) salts was prepared. Complex 1 has been characterized by X-ray single-crystal diffraction, PXRD, elemental analysis, infrared spectroscopy, thermogravimetric analysis, and solid-state UV-Vis absorption spectra. Complex 1 exhibits a three-dimensional (3D) framework structure based on the rod-shaped Zn-carboxylate/hydroxyl secondary building unit (SBU). Solid-state luminescence studies showed that 1 exhibits intense blue emission at room temperature. Interestingly, 1 could exhibit afterglow property only under low temperature (10 K) condition.
- MOFs,
- rod-shaped metal-SBU,
- luminescent properties,
- afterglow
1. [1]
  Eddaoudi M, Kim J, Yaghi O M. et al. Science, 2002, 295:469-472 doi: 10.1126/science.1067208
2. [2]
  Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004, 43:2334-2375 doi: 10.1002/(ISSN)1521-3773
3. [3]
  Li B Y, Leng K Y, Ma S Q, et al. J. Am. Chem. Soc., 2015, 137:4243-4248 doi: 10.1021/jacs.5b01352
4. [4]
  Chen B L, Xiang S C, Qian G D. Acc. Chem. Res., 2010, 43:1115-1124 doi: 10.1021/ar100023y
5. [5]
  Huang X D, Xu Y, Zheng L M, et al. Angew. Chem. Int. Ed., 2018, 58:8577-8581
6. [6]
  Weng D F, Wang Z M, Gao S. Chem. Soc. Rev., 2011, 40:3157-3181 doi: 10.1039/c0cs00093k
7. [7]
  Liu F L, Li D, Tao J, et al. Dalton Trans., 2018, 47:1407-1411 doi: 10.1039/C7DT04205A
8. [8]
  Cui Y J, Chen B L, Qian G D, et al. Acc. Chem. Res., 2016, 49:483-493 doi: 10.1021/acs.accounts.5b00530
9. [9]
  Sun C Y, Wang X L, Li J, et al. Nat. Commun., 2013, 4:2717-2723 doi: 10.1038/ncomms3717
10. [10]
  Chorazy S, Kumar K, Ohkoshi S, et al. Inorg. Chem., 2017, 56:5239-5252 doi: 10.1021/acs.inorgchem.7b00369
11. [11]
  Wang H, Lusting W P, Li J. Chem. Soc. Rev., 2018, 47:4729-4756 doi: 10.1039/C7CS00885F
12. [12]
  Cepeda J, Sebastian E S, Seco J M, et al. Chem. Commun., 2016, 52:8671-8674 doi: 10.1039/C6CC03242G
13. [13]
  Yuan S, Deng Y K, Sun D. Chem. Eur. J., 2014, 20:10093-10098 doi: 10.1002/chem.201402211
14. [14]
  Yang X G, Yan D P. Chem. Sci., 2016, 7:4519-4526 doi: 10.1039/C6SC00563B
15. [15]
  LIU Ying-Liang, LEI Bing-Fu, KUANG Jin-Yong, et al. Chinese J. Inorg. Chem., 2009, 25(8):1323-1329 doi: 10.3321/j.issn:1001-4861.2009.08.001
16. [16]
  Matsuzawa T, Aoko Y, Takeuchi N, et al. J. Electrochem. Soc., 1996, 143:2670-2673 doi: 10.1149/1.1837067
17. [17]
  Maragani R, Thomas M B, Misra R, et al. J. Phys. Chem. A, 2018, 122:4829-4837 doi: 10.1021/acs.jpca.8b02967
18. [18]
  Howarth A J, Davies D L, Wolf M O, et al. Inorg. Chem., 2014, 53:11882-11889 doi: 10.1021/ic501032t
19. [19]
  Han L, Qin L, Xu L P, et al. Inorg. Chem., 2013, 52:1667-1669 doi: 10.1021/ic301707h
20. [20]
  Luo F, Sun G M, Zheng A M, et al. Dalton Trans., 2012, 41:13280-13283 doi: 10.1039/c2dt31879b
21. [21]
  Gao M J, Yang P, Wu J Z, et al. CrystEngComm, 2012, 14:1264-1270 doi: 10.1039/C1CE06090B
22. [22]
  SADABS and SAINT, Program for Data Extraction and Reduction, Bruker AXS Inc., Madison, WI, USA, 2003.
23. [23]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
24. [24]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
25. [25]
  Yu M H, Hu T L, Bu X H. Inorg. Chem. Front., 2017, 4:256-260 doi: 10.1039/C6QI00362A
26. [26]
  WANG Peng-Fei. Chinese J. Inorg. Chem., 2018, 34(9):1747-1752
27. [27]
  Rosi N L, Kim J, Yaghi O M, et al. J. Am. Chem. Soc., 2005, 127:1504-1518 doi: 10.1021/ja045123o
28. [28]
  Wang Y L, Jiang Y L, Liu Q Y, et al. Dalton Trans., 2012, 41:11428-11437 doi: 10.1039/c2dt31090b
29. [29]
  Spek A L. PLATON:A Multipurpose Crystallographic Tool, Utrecht University, The Netherlands, 2001.
30. [30]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th Ed. New Jersey:John Wiley & Sons, Inc., 2009:61-67
31. [31]
  Liu L, Dai J C. Cryst. Growth Des., 2018, 18:4460-4469 doi: 10.1021/acs.cgd.8b00455
32. [32]
  Cui Y J, Qian G D, Chen B L, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
33. [33]
  Seco J M, Briones D, Cepeda J, et al. Cryst. Growth Des., 2017, 17:3893-3906 doi: 10.1021/acs.cgd.7b00522
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