Citation: LUAN Jing-Fei, TAN Wen-Cheng. Preparation, Photophysical and Photocatalytic Property Characterization of Sm₂FeSbO₇ during Visible Light Irradiation[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 1950-1965. doi: 10.11862/CJIC.2018.245 shu

Preparation, Photophysical and Photocatalytic Property Characterization of Sm₂FeSbO₇ during Visible Light Irradiation

LUAN Jing-Fei ^, ,
TAN Wen-Cheng

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

Corresponding author: LUAN Jing-Fei, jfluan@nju.edu.cn
Received Date: 17 May 2018
Revised Date: 14 August 2018

Figures(22)

In order to efficiently degrade organic pollutants in water, a new photocatalyst Sm₂FeSbO₇ was prepared by a solid-state reaction method for the first time. The construction and photocatalytic property of Sm₂FeSbO₇ had been characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, transmission electron microscope and UV-visible spectrometer. Sm₂FeSbO₇ crystallized with a pyrochlore-type structure, a cubic crystal system and a space group Fd3m. The lattice parameter a of Sm₂FeSbO₇ was 1.035 434 nm. The band gap of Sm₂FeSbO₇ was estimated to be 2.46 eV. The photocatalytic degradation of indigo carmine was accomplished under visible light irradiation with Sm₂FeSbO₇ as a catalyst compared with nitrogen-doped TiO₂. The results indicated that Sm₂FeSbO₇ displayed higher photocatalytic activity compared with nitrogen-doped TiO₂ for the photocatalytic degradation of indigo carmine under visible light irradiation. The reduction of the total organic carbon, the gradual formation of inorganic products, SO₄^2- and NO₃^-, and the evolution of CO₂ revealed the continuous mineralization of indigo carmine during the photocatalytic process. Some intermediate products which came from the photocatalytic degradation of indigo carmine were detected, such as o-nitrobenzoic acid and o-nitrobenzaldehyde, and a possible photocatalytic degradation path of indigo carmine was acquired.
- catalysis,
- Sm₂FeSbO₇,
- photocatalytic degradation,
- visible light irradiation,
- photodegradation pathway,
- indigo carmine
1. [1]
  Song Y L, Li J T, Bo B. Water Air Soil Pollut., 2010, 213(1/2/3/4):311-317
2. [2]
  Wang S B, Li H T. J. Hazard. Mater., 2005, 126:71-77 doi: 10.1016/j.jhazmat.2005.05.049
3. [3]
  Xu L, Wei Y G, Guo W, et al. Appl. Surf. Sci., 2015, 332:682-693 doi: 10.1016/j.apsusc.2015.01.235
4. [4]
  Zhang M Y, Shao C L, Guo Z C, et al. ACS Appl. Mater. Interfaces, 2011, 3:2573-2578 doi: 10.1021/am200412t
5. [5]
  Wang J, Li J, Zhang L Q, et al. Catal. Lett., 2009, 130(3/4):551-557
6. [6]
  Du H Y, Luan J F. Solid State Sci., 2012, 14:1295-1305 doi: 10.1016/j.solidstatesciences.2012.07.001
7. [7]
  Benshahar Y, Banin U. Top. Curr. Chem., 2016, 374(4):149-174
8. [8]
  Ahmad M, Ahmed E, Zhang Y W, et al. Curr. Appl. Phys., 2013, 13(4):697-704 doi: 10.1016/j.cap.2012.11.008
9. [9]
  Yao W F, Ye J H. Catal. Lett., 2006, 110(1/2):139-142
10. [10]
  Pena M E, Korfiatis G P, Patel M, et al. Water Res., 2005, 39(11):2327-2337 doi: 10.1016/j.watres.2005.04.006
11. [11]
  Pham T D, Lee B K. Appl. Surf. Sci., 2014, 296:15-23 doi: 10.1016/j.apsusc.2014.01.006
12. [12]
  Josephine G A S, Ramachandran S, Sivasamy A. J. Saudi Chem. Soc., 2015, 19(5):549-556 doi: 10.1016/j.jscs.2015.05.011
13. [13]
  Li J L, Liu T, Sui G Z, et al. J. Nanosci. Nanotechnol., 2015, 15(2):1408-1415 doi: 10.1166/jnn.2015.9611
14. [14]
  Chai Y Y, Wang L, Ren J. Appl. Surf. Sci., 2015, 324(45):212-220
15. [15]
  Yan C Y, Yi W T, Yuan H M, et al. Environ. Prog. Sustainable Energy, 2014, 33(2):419-429 doi: 10.1002/ep.v33.2
16. [16]
  Wen X J, Niu C G, Min R, et al. J. Colloid Interface Sci., 2017, 497:368-377 doi: 10.1016/j.jcis.2017.03.029
17. [17]
  Liang H R, Guo L J. Int. J. Hydrogen Energy, 2010, 35(13):7104-7109 doi: 10.1016/j.ijhydene.2010.01.037
18. [18]
  Song L M, Zhang S J, Chen B. Catal. Commun., 2009, 10(12):1565-1568 doi: 10.1016/j.catcom.2009.03.022
19. [19]
  Luan J F, Zheng S R, Hao X P, et al. J. Braz. Chem. Soc., 2006, 17(7):1368-1376 doi: 10.1590/S0103-50532006000700026
20. [20]
  Long M, Cai J, Cai W M, et al. Prog. Chem., 2006, 18(9):1065-1075
21. [21]
  Rawal S B, Bera S, Lee W I. Catal. Lett., 2012, 142:1482-1488 doi: 10.1007/s10562-012-0924-z
22. [22]
  Habibi-Yangjeh A, Shekofteh-Gohari M. Sep. Purif. Technol., 2017, 184:334-346 doi: 10.1016/j.seppur.2017.05.007
23. [23]
  Kalantari K, Ahmad M B, Masoumi H R, et al. Int. J. Mol. Sci., 2014, 15(7):12913-12927 doi: 10.3390/ijms150712913
24. [24]
  Vadivel S, Maruthamani D, Habibi-Yangjeh A, et al. J. Colloid Interface Sci., 2016, 480:126-136 doi: 10.1016/j.jcis.2016.07.012
25. [25]
  Huang L Z, Liu B S. RSC Adv., 2016, 6(22):17873-17879 doi: 10.1039/C5RA25689E
26. [26]
  Chakraborty A K, Kebede M A. React. Kinet., Mech Catal., 2012, 106(1):83-98
27. [27]
  Chai B, Peng T Y, Mao J, et al. Phys. Chem. Chem. Phys., 2012, 14:16745-16752 doi: 10.1039/c2cp42484c
28. [28]
  Bi J H, Fang W, Li L, et al. J. Alloys Compd., 2015, 649:28-34 doi: 10.1016/j.jallcom.2015.07.083
29. [29]
  Gouvêa C A, Wypych F, Moraes S G, et al. Chemosphere, 2000, 40(4):427-432 doi: 10.1016/S0045-6535(99)00312-4
30. [30]
  Tatsuma T, Saitoh S, Ngaotrakanwiwat P, et al. Langmuir, 2002, 18:7777-7779 doi: 10.1021/la026011i
31. [31]
  Ullah K, Meng Z D, Ye S, et al. J. Ind. Eng. Chem., 2014, 20(3):1035-1042 doi: 10.1016/j.jiec.2013.06.040
32. [32]
  Zhou J K, Zou Z G, Ray A K, et al. Ind. Eng. Chem. Res., 2007, 46:745-749 doi: 10.1021/ie0613220
33. [33]
  Zhang X, Ai Z H, Jia F L, et al. Mater. Chem. Phys., 2007, 103:162-167 doi: 10.1016/j.matchemphys.2007.02.008
34. [34]
  Zhang G K, Zou X, Gong J, et al. J. Alloys Compd., 2006, 425:76-80 doi: 10.1016/j.jallcom.2006.01.016
35. [35]
  Farrukh M A, Imran F, Ali S, et al. Russ. J. Appl. Chem., 2015, 88(9):1523-1527 doi: 10.1134/S1070427215090220
36. [36]
  Ghorai T K, Chakraborty M, Pramanik P. J. Alloys Compd., 2011, 509(32):8158-8164 doi: 10.1016/j.jallcom.2011.05.069
37. [37]
  Xie L J, Ma J F, Xu G J. Mater. Chem. Phys., 2008, 110:197-200 doi: 10.1016/j.matchemphys.2008.01.035
38. [38]
  Li X K, Kako T, Ye J H. Appl. Catal., A, 2007, 326:1-7 doi: 10.1016/j.apcata.2007.02.023
39. [39]
  Shetty K, Prathibha B S, Rangappa D, et al. Mater. Today, 2017, 4(11):11764-11772 doi: 10.1016/j.matpr.2017.09.093
40. [40]
  Jiang Y Y, Zhang J W, Hu Z Q, et al. Appl. Mech. Mater., 2014, 455:99-105
41. [41]
  Chen C H, Liang Y H, Zhang W D. J. Alloys Compd., 2010, 501:168-172 doi: 10.1016/j.jallcom.2010.04.072
42. [42]
  Qiu J X, Wang C Y, Gu M Y. Mater. Sci. Eng. B, 2004, 112:1-4 doi: 10.1016/j.mseb.2004.04.012
43. [43]
  Marugan J, Hufschmidt D, Sagawe G, et al. Water Res., 2006, 40:833-839 doi: 10.1016/j.watres.2005.12.019
44. [44]
  Sakthivel S, Shankar M V, Palanichamy M, et al. Water Res., 2004, 38:3001-3008 doi: 10.1016/j.watres.2004.04.046
45. [45]
  Izumi F. Rigaku J., 1989, 6(1):10-20
46. [46]
  Tauc J, Grigorovici R, Vancu A. Phys. Status Solidi, 1966, 15:627-637 doi: 10.1002/(ISSN)1521-3951
47. [47]
  Luan J F, Wang S, Ma K, et al. J. Phys. Chem. C, 2010, 114:9398-9407
48. [48]
  Yang Y J, Luan J F. Molecules, 2012, 17:2752-2772 doi: 10.3390/molecules17032752
49. [49]
  Chang M J, Wang H, Li H L, et al. J. Mater. Sci., 2018, 53:3682-3691 doi: 10.1007/s10853-017-1813-z
50. [50]
  Lachheb H, Puzenat E, Houas A, et al. Appl. Catal., B, 2002, 39:75-90 doi: 10.1016/S0926-3373(02)00078-4
51. [51]
  ZHANG Xiao-He, CHEN Guo-Qing, MA Chao-Qun. Laser and Optoelectronics Progress, 2018, 55(1):013007(5 Pages)
52. [52]
  Qu R J, Xu B Z, Meng L J, et al. Water Res., 2015, 68:316-327 doi: 10.1016/j.watres.2014.10.017
53. [53]
  Huang S Q, Xu Y G, Xie M, et al. Colloids Surf. A, 2015, 478(ISSN):71-80
54. [54]
  Subash B, Krishnakumar B, Swaminathan M, et al. Langmuir, 2013, 29:939-949 doi: 10.1021/la303842c
55. [55]
  Sun H Q, Zhou G L, Liu S Z, et al. Chem. Eng. J., 2013, 231(9):18-25
56. [56]
  Ding H M, Sun H, Shan Y K. J. Photochem. Photobiol. A, 2005, 169:101-107 doi: 10.1016/j.jphotochem.2004.04.015
57. [57]
  Gadhi T A, Hernández-Gordillo A, Bizarro M, et al. Ceram. Int., 2016, 42(11):13065-13073 doi: 10.1016/j.ceramint.2016.05.087
58. [58]
  Wiegel M, Middel W, Blasse G. J. Mater. Chem., 1995, 5(7):981-983 doi: 10.1039/jm9950500981
1. [1]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
2. [2]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
3. [3]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
4. [4]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
5. [5]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
6. [6]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
7. [7]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
8. [8]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
9. [9]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
10. [10]
  Tian-Yu Gao , Xiao-Yan Mo , Shu-Rong Zhang , Yuan-Xu Jiang , Shu-Ping Luo , Jian-Heng Ye , Da-Gang Yu . Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO₂. Chinese Chemical Letters, 2024, 35(7): 109364-. doi: 10.1016/j.cclet.2023.109364
11. [11]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
12. [12]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
13. [13]
  Yuhao Guo , Na Li , Tingjiang Yan . Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides. Chinese Journal of Structural Chemistry, 2024, 43(7): 100320-100320. doi: 10.1016/j.cjsc.2024.100320
14. [14]
  Yi Luo , Lin Dong . Multicomponent remote C(sp²)-H bond addition by Ru catalysis: An efficient access to the alkylarylation of 2H-imidazoles. Chinese Chemical Letters, 2024, 35(10): 109648-. doi: 10.1016/j.cclet.2024.109648
15. [15]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
16. [16]
  Yu Mao , Yilin Liu , Xiaochen Wang , Shengyang Ni , Yi Pan , Yi Wang . Acylfluorination of enynes via phosphine and silver catalysis. Chinese Chemical Letters, 2024, 35(8): 109443-. doi: 10.1016/j.cclet.2023.109443
17. [17]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
18. [18]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
19. [19]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
20. [20]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(253)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, Photophysical and Photocatalytic Property Characterization of Sm2FeSbO7 during Visible Light Irradiation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation, Photophysical and Photocatalytic Property Characterization of Sm₂FeSbO₇ during Visible Light Irradiation