Citation: HOU Xue-Dan, GUO Shou-Wu, WANG Qian, WANG Xiao-Fei. Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1910-1916. doi: 10.11862/CJIC.2018.237 shu

Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries

1.
School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi′an 710021, China
2.
School of Materials Science and Chemical Engineering, Xi′an Technological University, Xi′an 710021, China

Corresponding author: GUO Shou-Wu, swguo@sjtu.edu.cn WANG Xiao-Fei, wangxiaof@sust.edu.cn
Received Date: 15 May 2018
Revised Date: 17 August 2018

Figures(4)

Bulk Ni₃Mn-layered double hydroxides (Ni₃Mn-LDHs) was exfoliated into single-layer Ni₃Mn-LDHs nanosheets via liquid phase exfoliation, and then incorporated with CNT to obtain Ni₃Mn-LDHs/CNT composites by self-assemble method. The structure of the composites was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical process was analyzed by galvanostatic tests, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The Ni₃Mn-LDHs/CNT composites improved the ORR and OER catalytic activities significantly, the obtained Ni₃Mn-LDHs/CNT cathode presented nearly 300% higher discharge capacity, excellent rate and cycling stability than the CNT cathode in lithium-oxygen batteries.
- composite materials,
- lithium-oxygen batteries,
- catalyst,
- functional
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Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries